Deposition and characterization of Cu9S5 nanocrystals from unsymmetrical [(Hex)(Me)NC(S)NC(O)C6H3(NO2)2-3,5]2Cu(II) and [(Et)(Bu)NC(S)NC(O)C6H4-4-NO2]2Cu(II) complexes by colloidal thermolysis method

Sohail SAEED; Rizwan HUSSAIN

Makale detayları

Deposition and characterization of Cu9S5 nanocrystals from unsymmetrical [(Hex)(Me)NC(S)NC(O)C6H3(NO2)2-3,5]2Cu(II) and [(Et)(Bu)NC(S)NC(O)C6H4-4-NO2]2Cu(II) complexes by colloidal thermolysis method

Yazarlar:

Sohail SAEED | Rizwan HUSSAIN

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Chemistry 2014 Vol.38 Issue 3, pp.413-422

Belge Tipi:

Makale

Yayın Tarihi:

5/2014

Belge Dili:

Türkçe

Document ID (Org No.):

2000727160

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527

Özet:

 

Cu9S5 nanocrystals were synthesized from unsymmetrical [(Hex)(Me)NC(S)NC(O)C6H3(NO2)2-3,5]2Cu(II) and [(Et)(Bu)NC(S)NC(O)C6H4-4-NO2]2 Cu(II) complexes by colloidal thermolysis in the presence of surfactant oleylamine. The unsymmetrical copper complexes were synthesized by the reaction of copper(II) acetate with N-[hexyl(methyl)carbamothioyl]-3,5-dinitrobenzamide and N-[ethyl(butyl)carbamothioyl]-4-nitrobenzamide. The complexes were used as single-source precursors for the preparation of Cu9S5 nanocrsytals. The Cu9S5 nanocrystals were characterized by X-ray powder diffraction and transmission electron microscopy.

 

Cu9S5 nanocrystals were synthesized from unsymmetrical [(Hex)(Me)NC(S)NC(O)C6H3(NO2)2-3,5]2Cu(II) and [(Et)(Bu)NC(S)NC(O)C6H4-4-NO2]2 Cu(II) complexes by colloidal thermolysis in the presence of surfactant oleylamine. The unsymmetrical copper complexes were synthesized by the reaction of copper(II) acetate with N-[hexyl(methyl)carbamothioyl]-3,5-dinitrobenzamide and N-[ethyl(butyl)carbamothioyl]-4-nitrobenzamide. The complexes were used as single-source precursors for the preparation of Cu9S5 nanocrsytals. The Cu9S5 nanocrystals were characterized by X-ray powder diffraction and transmission electron microscopy.

Makale detayları

Deposition and characterization of Cu9S5 nanocrystals from unsymmetrical [(Hex)(Me)NC(S)NC(O)C6H3(NO2)2-3,5]2Cu(II) and [(Et)(Bu)NC(S)NC(O)C6H4-4-NO2]2Cu(II) complexes by colloidal thermolysis method

Yazarlar: Sohail SAEED | Rizwan HUSSAIN

Yayıncı: TUBITAK

Dergi: Turkish Journal of Chemistry 2014 Vol.38 Issue 3, pp.413-422

Belge Tipi: Makale

Yayın Tarihi: 5/2014

Belge Dili: Türkçe

Document ID (Org No.): 2000727160

Sıklık: İki Aylık

eISSN: 1303-6130

pISSN: 1300-0527

Sayı

Yazarlar:

Sohail SAEED | Rizwan HUSSAIN

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Chemistry 2014 Vol.38 Issue 3, pp.413-422

Belge Tipi:

Makale

Yayın Tarihi:

5/2014

Belge Dili:

Türkçe

Document ID (Org No.):

2000727160

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527