Studies on synthesis of boron and carborane cage derivatives

Sevban DOĞAN; Akın AKDAĞ

doi:https://doi.org/10.30728/boron.641589

Makale detayları

Studies on synthesis of boron and carborane cage derivatives

Yazarlar:

Sevban DOĞAN | Akın AKDAĞ

Yayıncı:

TENMAK Bor Araştırma Enstitüsü

Ana Başlıklar:

Uygulamalı fizik

Dergi:

Journal of Boron 2020 Vol.5 Issue 1, pp.1-11

Belge Tipi:

Makale

Yayın Tarihi:

3/2020

Belge Dili:

İngilizce

Document ID (Org No.):

2000705173

Sıklık:

Aylık

eISSN:

2667-8438

pISSN:

2149-9020

DOI:

https://doi.org/10.30728/boron.641589

Özet:

 


Weakly coordinating anions are extremely versatile species for capturing and characterizing cationic intermediates. Among these anions, carboranes and some boranes are known to be the most weakly coordinating anions. In this study, the carboranes and boranes were synthesized in order to use in different fields. B11H14- was synthesized from NaBH4 and used to synthesize CB11H12-. CB11H12- was synthesized by carbene addition to undecaborate. B11H14- was converted to B10H14 by oxidation and extrusion of one boron vertex. CB11H12- was methylated on boron vertex to get HCB11Me11-. The methylated carborane cages are more hydrophobic and weakly coordinating anions. 


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Makale detayları

Studies on synthesis of boron and carborane cage derivatives

Yazarlar: Sevban DOĞAN | Akın AKDAĞ

Yayıncı: TENMAK Bor Araştırma Enstitüsü

Ana Başlıklar: Uygulamalı fizik

Dergi: Journal of Boron 2020 Vol.5 Issue 1, pp.1-11

Belge Tipi: Makale

Yayın Tarihi: 3/2020

Belge Dili: İngilizce

Document ID (Org No.): 2000705173

Sıklık: Aylık

eISSN: 2667-8438

pISSN: 2149-9020

DOI: https://doi.org/10.30728/boron.641589

Sayı

Yazarlar:

Sevban DOĞAN | Akın AKDAĞ

Yayıncı:

TENMAK Bor Araştırma Enstitüsü

Ana Başlıklar:

Uygulamalı fizik

Dergi:

Journal of Boron 2020 Vol.5 Issue 1, pp.1-11

Belge Tipi:

Makale

Yayın Tarihi:

3/2020

Belge Dili:

İngilizce

Document ID (Org No.):

2000705173

Sıklık:

Aylık

eISSN:

2667-8438

pISSN:

2149-9020

DOI:

https://doi.org/10.30728/boron.641589