Chemical Potential vs. Gibbs Free Energy Relationship by Redlich and Kister and the Redlich-Kister Polynomial

Helfried NÄFE

doi:https://doi.org/10.5541/ijot.575

Makale detayları

Chemical Potential vs. Gibbs Free Energy Relationship by Redlich and Kister and the Redlich-Kister Polynomial

Yazarlar:

Helfried NÄFE

Yayıncı:

Uluslararası Uygulamalı Termodinamik Derneği İktisadi İşletmesi

Dergi:

International Journal of Thermodynamics 2014 Vol.17 Issue 4, pp.250-255

Belge Tipi:

Makale

Yayın Tarihi:

2/2014

Belge Dili:

İngilizce

Document ID (Org No.):

2000476867

Sıklık:

Üç Aylık

eISSN:

2146-1511

pISSN:

1301-9724

DOI:

https://doi.org/10.5541/ijot.575

Özet:

 

The relationship of Redlich and Kister between the chemical potential and the molar Gibbs free energy of a multicomponent mixture proves to be in contradiction with both fundamental concepts of chemical thermodynamics and mathematical principles. Hence, it is invalid. This invalidity corresponds with the thermodynamically inadequate representation of the prevalent Redlich-Kister polynomial for the mole fraction dependence of the excess Gibbs free energy of a mixture.

Makale detayları

Chemical Potential vs. Gibbs Free Energy Relationship by Redlich and Kister and the Redlich-Kister Polynomial

Yazarlar: Helfried NÄFE

Yayıncı: Uluslararası Uygulamalı Termodinamik Derneği İktisadi İşletmesi

Dergi: International Journal of Thermodynamics 2014 Vol.17 Issue 4, pp.250-255

Belge Tipi: Makale

Yayın Tarihi: 2/2014

Belge Dili: İngilizce

Document ID (Org No.): 2000476867

Sıklık: Üç Aylık

eISSN: 2146-1511

pISSN: 1301-9724

DOI: https://doi.org/10.5541/ijot.575

Sayı

Yazarlar:

Helfried NÄFE

Yayıncı:

Uluslararası Uygulamalı Termodinamik Derneği İktisadi İşletmesi

Dergi:

International Journal of Thermodynamics 2014 Vol.17 Issue 4, pp.250-255

Belge Tipi:

Makale

Yayın Tarihi:

2/2014

Belge Dili:

İngilizce

Document ID (Org No.):

2000476867

Sıklık:

Üç Aylık

eISSN:

2146-1511

pISSN:

1301-9724

DOI:

https://doi.org/10.5541/ijot.575