SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF BIDENTATE SCHIFF BASE AND ZINC(II) COMPLEX

Selma YILDIRIM UÇAN

Makale detayları

SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF BIDENTATE SCHIFF BASE AND ZINC(II) COMPLEX

Yazarlar:

Selma YILDIRIM UÇAN

Yayıncı:

Nigde Omer Halisdemir University

Ana Başlıklar:

Fizik

Dergi:

Eurasian Journal of Science Engineering and Technology 2020 Vol.1 Issue 1, pp.35-40

Belge Tipi:

Makale

Yayın Tarihi:

11/2020

Belge Dili:

İngilizce

Document ID (Org No.):

2000423210

eISSN:

2718-0883

Özet:

 

A new asymmetric bidentate Schiff base ligand was synthesized from 4-Methoxysalicylaldehyde. The complex was prepared by adding Zn(II) acetate salt dissolved in methanol to the Schiff base ligand. The ligand and its metal complex were characterized by elemental analysis (CHN), FT-IR, UV-Vis spectroscopy, 1H NMR, TG/DTG, SEM and conductometric measurements. The spectroscopic data reveals that the Zn(II) atom in the center of the complex is four-coordinated by two phenolic oxygen atoms and two azomethine nitrogen atoms of two Schiff base ligands. The Zn(II) complex is diamagnetic as expected for d10 metal ions in a tetrahedral geometry. The Zn(II) complex is soluble in DMSO and DMF and is insoluble in acetone, chloroform, ethanol and methanol. The conductance data indicate that the complex is non-electrolytes.

Makale detayları

SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF BIDENTATE SCHIFF BASE AND ZINC(II) COMPLEX

Yazarlar: Selma YILDIRIM UÇAN

Yayıncı: Nigde Omer Halisdemir University

Ana Başlıklar: Fizik

Dergi: Eurasian Journal of Science Engineering and Technology 2020 Vol.1 Issue 1, pp.35-40

Belge Tipi: Makale

Yayın Tarihi: 11/2020

Belge Dili: İngilizce

Document ID (Org No.): 2000423210

eISSN: 2718-0883

Sayı

Yazarlar:

Selma YILDIRIM UÇAN

Yayıncı:

Nigde Omer Halisdemir University

Ana Başlıklar:

Fizik

Dergi:

Eurasian Journal of Science Engineering and Technology 2020 Vol.1 Issue 1, pp.35-40

Belge Tipi:

Makale

Yayın Tarihi:

11/2020

Belge Dili:

İngilizce

Document ID (Org No.):

2000423210

eISSN:

2718-0883