Synthesis of some ketones via nano-nickel oxide catalyzed acylation of   arylzinc reagents; strategy involving the use of mixed (methyl)(aryl)zincs

Özgen Ömür PEKEL; Ender ERDİK; Melike KALKAN

Makale detayları

Synthesis of some ketones via nano-nickel oxide catalyzed acylation of arylzinc reagents; strategy involving the use of mixed (methyl)(aryl)zincs

Yazarlar:

Özgen Ömür PEKEL | Ender ERDİK | Melike KALKAN

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Chemistry 2018 Vol.42 Issue 3, pp.759-767

Belge Tipi:

Makale

Yayın Tarihi:

5/2018

Belge Dili:

Türkçe

Document ID (Org No.):

2000726107

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527

Özet:

 

Nano-NiO catalyzed acylation of mixed (methyl)(aryl)zincs with aromatic acyl   halides in THF at room temperature provides a new facile route for   aryl-aroyl coupling. Among NiCl22_{2}.L22_{2} and NiCl22_{2}.L (L =   monodentate and bidentate phosphine ligand) catalysts, the lower catalyst   loading of NiCl22_{2} (dppf) may seem attractive;   however, nano-NiO, being the lowest cost catalyst, is more favorable for   aroylation of (methyl)(aryl)zincs. This procedure also provides a supplement   to Cu and Pd catalyzed acylation of diorganozincs.

Makale detayları

Synthesis of some ketones via nano-nickel oxide catalyzed acylation of arylzinc reagents; strategy involving the use of mixed (methyl)(aryl)zincs

Yazarlar: Özgen Ömür PEKEL | Ender ERDİK | Melike KALKAN

Yayıncı: TUBITAK

Dergi: Turkish Journal of Chemistry 2018 Vol.42 Issue 3, pp.759-767

Belge Tipi: Makale

Yayın Tarihi: 5/2018

Belge Dili: Türkçe

Document ID (Org No.): 2000726107

Sıklık: İki Aylık

eISSN: 1303-6130

pISSN: 1300-0527

Sayı

Yazarlar:

Özgen Ömür PEKEL | Ender ERDİK | Melike KALKAN

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Chemistry 2018 Vol.42 Issue 3, pp.759-767

Belge Tipi:

Makale

Yayın Tarihi:

5/2018

Belge Dili:

Türkçe

Document ID (Org No.):

2000726107

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527