Bifunctional Allyl-Sulphonium Salt as a Novel Addition--Fragmentation Agent for Photoinitiated Cationic Polymerization

Utku KÜÇÜKTÖNBEKİCİ; Mustafa DEĞİRMENCİ; Yusuf YAĞCI

Makale detayları

Bifunctional Allyl-Sulphonium Salt as a Novel Addition--Fragmentation Agent for Photoinitiated Cationic Polymerization

Yazarlar:

Utku KÜÇÜKTÖNBEKİCİ | Mustafa DEĞİRMENCİ | Yusuf YAĞCI

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Chemistry 2002 Vol.26 Issue 5, pp.793-800

Belge Tipi:

Makale

Yayın Tarihi:

4/2002

Belge Dili:

Türkçe

Document ID (Org No.):

2000729801

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527

Özet:

 

Bifunctional allyl tetrahydrothiophenium hexafluoroantimonate was  synthesized via a one-pot reaction of 3-chloro-2-chloromethylpropene  with thiophene in the presence of sodium hexafluoroantimonate.  The  initiation capability of this salt, in conjunction with a  photochemical free radical source such as 2,2-dimethoxy-2-phenyl  acetophenone and benzophenone, via an addition-fragmentation mechanism  in the cationic polymerization of cyclohexene oxide and butyl  vinyl ether is investigated.

 

Bifunctional allyl tetrahydrothiophenium hexafluoroantimonate was  synthesized via a one-pot reaction of 3-chloro-2-chloromethylpropene  with thiophene in the presence of sodium hexafluoroantimonate.  The  initiation capability of this salt, in conjunction with a  photochemical free radical source such as 2,2-dimethoxy-2-phenyl  acetophenone and benzophenone, via an addition-fragmentation mechanism  in the cationic polymerization of cyclohexene oxide and butyl  vinyl ether is investigated.

Makale detayları

Bifunctional Allyl-Sulphonium Salt as a Novel Addition--Fragmentation Agent for Photoinitiated Cationic Polymerization

Yazarlar: Utku KÜÇÜKTÖNBEKİCİ | Mustafa DEĞİRMENCİ | Yusuf YAĞCI

Yayıncı: TUBITAK

Dergi: Turkish Journal of Chemistry 2002 Vol.26 Issue 5, pp.793-800

Belge Tipi: Makale

Yayın Tarihi: 4/2002

Belge Dili: Türkçe

Document ID (Org No.): 2000729801

Sıklık: İki Aylık

eISSN: 1303-6130

pISSN: 1300-0527

Sayı

Yazarlar:

Utku KÜÇÜKTÖNBEKİCİ | Mustafa DEĞİRMENCİ | Yusuf YAĞCI

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Chemistry 2002 Vol.26 Issue 5, pp.793-800

Belge Tipi:

Makale

Yayın Tarihi:

4/2002

Belge Dili:

Türkçe

Document ID (Org No.):

2000729801

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527