Synthesis and structural properties of NNN-3,4-(dichlorophenyl)-3-oxo-3- phenyl-2-(phenylcarbonyl)propanamide and its Cu(II) complex

Ahmet Oral SARIOĞLU; Tuğba Taşkin TOK; Mehmet AKKURT; Muhammad Nawaz TAHIR; Mehmet SÖNMEZ

Makale detayları

Synthesis and structural properties of NNN-3,4-(dichlorophenyl)-3-oxo-3- phenyl-2-(phenylcarbonyl)propanamide and its Cu(II) complex

Yazarlar:

Ahmet Oral SARIOĞLU | Tuğba Taşkin TOK | Mehmet AKKURT | Muhammad Nawaz TAHIR | Mehmet SÖNMEZ

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Chemistry 2016 Vol.40 Issue 1, pp.76-92

Belge Tipi:

Makale

Yayın Tarihi:

1/2016

Belge Dili:

Türkçe

Document ID (Org No.):

2000726683

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527

Özet:

 

A new N-carboxamide compound (3) was synthesized by the reaction of dibenzoylaceticacid-NNN-carboxyethyla\-mide (1) and 3,4-dichloroaniline (2). The NNN-(3,4-dichlorophenyl)-3-oxo-3-phenyl-2-(phenylcarbonyl) propanamide (3) subsequently reacted with Cu salt to produce its Cu(II) complex compound (4). The compounds were characterized by analytical and spectral methods. In addition, X-ray diffraction was performed to characterize and obtain detailed information about the structure of 3. The fully optimized geometries of compounds 3 and 4 were calculated at different basis sets by using the Gaussian09 (G09) software to investigate their 3D geometries and electronic structures. Comparisons between the calculated and experimental data including molecular structures, fundamental vibrational modes, and electronic properties were made. The comparisons showed that the theoretical data were compatible with the corresponding experimental values of compounds 3 and 4.

Makale detayları

Synthesis and structural properties of NNN-3,4-(dichlorophenyl)-3-oxo-3- phenyl-2-(phenylcarbonyl)propanamide and its Cu(II) complex

Yazarlar: Ahmet Oral SARIOĞLU | Tuğba Taşkin TOK | Mehmet AKKURT | Muhammad Nawaz TAHIR | Mehmet SÖNMEZ

Yayıncı: TUBITAK

Dergi: Turkish Journal of Chemistry 2016 Vol.40 Issue 1, pp.76-92

Belge Tipi: Makale

Yayın Tarihi: 1/2016

Belge Dili: Türkçe

Document ID (Org No.): 2000726683

Sıklık: İki Aylık

eISSN: 1303-6130

pISSN: 1300-0527

Sayı

Yazarlar:

Ahmet Oral SARIOĞLU | Tuğba Taşkin TOK | Mehmet AKKURT | Muhammad Nawaz TAHIR | Mehmet SÖNMEZ

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Chemistry 2016 Vol.40 Issue 1, pp.76-92

Belge Tipi:

Makale

Yayın Tarihi:

1/2016

Belge Dili:

Türkçe

Document ID (Org No.):

2000726683

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527