N-BUTYL SUBSTITUTED N-HETEROCYCLIC CARBENE-PD(II)-PYRIDINE (PEPPSI) COMPLEXES:  SYNTHESIS, CHARACTERIZATION AND CATALYTIC ACTIVITY IN THE SUZUKI-MIYAURA REACTION

Rukiye Fırıncı

doi:https://doi.org/10.18596/jotcsa.90024

Makale detayları

N-BUTYL SUBSTITUTED N-HETEROCYCLIC CARBENE-PD(II)-PYRIDINE (PEPPSI) COMPLEXES: SYNTHESIS, CHARACTERIZATION AND CATALYTIC ACTIVITY IN THE SUZUKI-MIYAURA REACTION

Yazarlar:

Rukiye Fırıncı

Yayıncı:

Turkish Chemical Society

Dergi:

Journal of the Turkish Chemical Society Section A: Chemistry 2016 Vol.3 Issue 3, pp.93-104

Belge Tipi:

Makale

Yayın Tarihi:

1/2017

Belge Dili:

Türkçe

Document ID (Org No.):

2000503734

Sıklık:

Üç Aylık

eISSN:

2149-0120

DOI:

https://doi.org/10.18596/jotcsa.90024

Özet:

 


A series of N-butyl substituted imidazolium salts, (1a-c) and their pyridine enhanced precatalyst preparation stabilization and initiation (PEPPSI) themed palladium N-heterocyclic carbene complexes (2a-c) were synthesized and characterized. Pd-NHC complexes were fully determined by elemental analysis and spectroscopic. The synthesized complexes were tested in Suzuki-Miyaura cross-coupling reaction. These complexes were found to be efficient catalysts for the Suzuki-Miyaura reaction of phenylboronic acid with aryl bromides.

 

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Makale detayları

N-BUTYL SUBSTITUTED N-HETEROCYCLIC CARBENE-PD(II)-PYRIDINE (PEPPSI) COMPLEXES: SYNTHESIS, CHARACTERIZATION AND CATALYTIC ACTIVITY IN THE SUZUKI-MIYAURA REACTION

Yazarlar: Rukiye Fırıncı

Yayıncı: Turkish Chemical Society

Dergi: Journal of the Turkish Chemical Society Section A: Chemistry 2016 Vol.3 Issue 3, pp.93-104

Belge Tipi: Makale

Yayın Tarihi: 1/2017

Belge Dili: Türkçe

Document ID (Org No.): 2000503734

Sıklık: Üç Aylık

eISSN: 2149-0120

DOI: https://doi.org/10.18596/jotcsa.90024

Sayı

Yazarlar:

Rukiye Fırıncı

Yayıncı:

Turkish Chemical Society

Dergi:

Journal of the Turkish Chemical Society Section A: Chemistry 2016 Vol.3 Issue 3, pp.93-104

Belge Tipi:

Makale

Yayın Tarihi:

1/2017

Belge Dili:

Türkçe

Document ID (Org No.):

2000503734

Sıklık:

Üç Aylık

eISSN:

2149-0120

DOI:

https://doi.org/10.18596/jotcsa.90024