New soluble amidoamine substituted phthalocyanines: synthesis, characterization, and investigation of their solution properties

Senem ÇOLAK; Salih Zeki YILDIZ

doi:https://doi.org/10.3906/kim-1406-61

Makale detayları

New soluble amidoamine substituted phthalocyanines: synthesis, characterization, and investigation of their solution properties

Yazarlar:

Senem ÇOLAK | Salih Zeki YILDIZ

Yayıncı:

TUBITAK

Ana Başlıklar:

Uygulamalı fizik

Dergi:

Turkish Journal of Chemistry 2014 Vol.38 Issue 6, pp.1153-1165

Belge Tipi:

Makale

Yayın Tarihi:

5/2014

Belge Dili:

İngilizce

Document ID (Org No.):

2000727042

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527

DOI:

https://doi.org/10.3906/kim-1406-61

Özet:

 

The synthesis of tetraaminopropylamid substituted phthalocyanines was targeted to prepare enhanced soluble phthalocyanines in common solvents from hydrophobic to hydrophilic that bore nonionic groups on their periphery. Metal-free (H2Pc) and metallophthalocyanines (Zn(II) (ZnPc), Cu(II) (CuPc) and Co(II) (CoPc)) were prepared and characterized by UV-Vis, FT-IR, and mass spectroscopies. The 1H NMR spectra were recorded for the diamagnetic phthalocyanine species H2Pc and ZnPc. The phthalocyanines showed sufficient solubility in common organic solvents such as dimethyl sulfoxide, tetrahydrofuran, and ethanol. However, methanol was not a good solvent for CuPc and H2Pc. Solubility and aggregation studies of H2Pc and ZnPc were performed in different solvents and different concentrations in DMF. The solubility in water was also examined by altering pH to exhibit solubility characteristic in polar solvents for H2Pc and ZnPc.

 

The synthesis of tetraaminopropylamid substituted phthalocyanines was targeted to prepare enhanced soluble phthalocyanines in common solvents from hydrophobic to hydrophilic that bore nonionic groups on their periphery. Metal-free (H2Pc) and metallophthalocyanines (Zn(II) (ZnPc), Cu(II) (CuPc) and Co(II) (CoPc)) were prepared and characterized by UV-Vis, FT-IR, and mass spectroscopies. The 1H NMR spectra were recorded for the diamagnetic phthalocyanine species H2Pc and ZnPc. The phthalocyanines showed sufficient solubility in common organic solvents such as dimethyl sulfoxide, tetrahydrofuran, and ethanol. However, methanol was not a good solvent for CuPc and H2Pc. Solubility and aggregation studies of H2Pc and ZnPc were performed in different solvents and different concentrations in DMF. The solubility in water was also examined by altering pH to exhibit solubility characteristic in polar solvents for H2Pc and ZnPc.

Makale detayları

New soluble amidoamine substituted phthalocyanines: synthesis, characterization, and investigation of their solution properties

Yazarlar: Senem ÇOLAK | Salih Zeki YILDIZ

Yayıncı: TUBITAK

Ana Başlıklar: Uygulamalı fizik

Dergi: Turkish Journal of Chemistry 2014 Vol.38 Issue 6, pp.1153-1165

Belge Tipi: Makale

Yayın Tarihi: 5/2014

Belge Dili: İngilizce

Document ID (Org No.): 2000727042

Sıklık: İki Aylık

eISSN: 1303-6130

pISSN: 1300-0527

DOI: https://doi.org/10.3906/kim-1406-61

Sayı

Yazarlar:

Senem ÇOLAK | Salih Zeki YILDIZ

Yayıncı:

TUBITAK

Ana Başlıklar:

Uygulamalı fizik

Dergi:

Turkish Journal of Chemistry 2014 Vol.38 Issue 6, pp.1153-1165

Belge Tipi:

Makale

Yayın Tarihi:

5/2014

Belge Dili:

İngilizce

Document ID (Org No.):

2000727042

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527

DOI:

https://doi.org/10.3906/kim-1406-61