Syntheses and characterizations of cyclotriphosphazenes containing a 4-oxy-1-naphthaldehyde group

Hanife İBİŞOĞLU; Esra TANRIVERDİ EÇİK; Gönül YENİLMEZ ÇİFTÇİ

Makale detayları

Syntheses and characterizations of cyclotriphosphazenes containing a 4-oxy-1-naphthaldehyde group

Yazarlar:

Hanife İBİŞOĞLU | Esra TANRIVERDİ EÇİK | Gönül YENİLMEZ ÇİFTÇİ

Yayıncı:

TUBITAK

Ana Başlıklar:

Uygulamalı fizik

Dergi:

Turkish Journal of Chemistry 2018 Vol.42 Issue 4, pp.1174-1183

Belge Tipi:

Makale

Yayın Tarihi:

8/2018

Belge Dili:

İngilizce

Document ID (Org No.):

2000726068

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527

Özet:

 


 
                         The nucleophilic substitution reaction of 
hexachlorocyclotriphosphazene (N3     3    33_{3}P3     3    33_{3}Cl6     6    66_{6}, trimer) (1) 
with 4-hydroxy-1-naphthaldehyde (2) has been investigated for the 
first time. 4′′^{{\prime}} -Oxy-1′     ′    ′′^{{\prime}} -naphthaldehyde substituted mono- 
(3), bis- (4), and tris- (5) cyclotriphosphazenes 
were obtained from the nucleophilic substitution of compound 1 with 
2 in a 1:2 molar ratio in the presence of Cs2     2    22_{2}CO3     3    33_{3} in 
acetone at reflux. The pentakis-(6) and hexakis-substituted 
(7) cyclotriphosphazenes were prepared from the reaction of 
1 with 2 in a 1:7 molar ratio using K2     2    22_{2}CO3     3    33_{3} as a 
proton abstractor in tetrahydrofuran at room temperature. The structures of 
the new compounds (3-7) were determined by elemental 
analysis, FT-IR, and mass and nuclear magnetic resonance (1    1   11^{1}H and 
31    31   3131^{31}P) spectroscopies.
                    

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Makale detayları

Syntheses and characterizations of cyclotriphosphazenes containing a 4-oxy-1-naphthaldehyde group

Yazarlar: Hanife İBİŞOĞLU | Esra TANRIVERDİ EÇİK | Gönül YENİLMEZ ÇİFTÇİ

Yayıncı: TUBITAK

Ana Başlıklar: Uygulamalı fizik

Dergi: Turkish Journal of Chemistry 2018 Vol.42 Issue 4, pp.1174-1183

Belge Tipi: Makale

Yayın Tarihi: 8/2018

Belge Dili: İngilizce

Document ID (Org No.): 2000726068

Sıklık: İki Aylık

eISSN: 1303-6130

pISSN: 1300-0527

Sayı

Yazarlar:

Hanife İBİŞOĞLU | Esra TANRIVERDİ EÇİK | Gönül YENİLMEZ ÇİFTÇİ

Yayıncı:

TUBITAK

Ana Başlıklar:

Uygulamalı fizik

Dergi:

Turkish Journal of Chemistry 2018 Vol.42 Issue 4, pp.1174-1183

Belge Tipi:

Makale

Yayın Tarihi:

8/2018

Belge Dili:

İngilizce

Document ID (Org No.):

2000726068

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527