Artificial neural network approach for lead removal from aqueous solution by agricultural waste derived biochars

Nihan Kaya; Fatma Erdem

Makale detayları

Artificial neural network approach for lead removal from aqueous solution by agricultural waste derived biochars

Yazarlar:

Nihan Kaya | Fatma Erdem

Yayıncı:

Yildiz Technical University

Ana Başlıklar:

Computer Software

Dergi:

Sigma Journal of Engineering and Natural Sciences Vol.41 Issue 1, pp.64-73

Belge Tipi:

Makale

Yayın Tarihi:

3/2023

Belge Dili:

İngilizce

Document ID (Org No.):

2001304941

pISSN:

1304-7191

Anahtar kelimeler:

Özet:

 Lead Pb2 which is one of the most important heavy metals found in water sources, has a toxic effect on living things in aquatic environment. Therefore, the removal of Pb2 ions from wastewater is very important if its concentration is above the determined discharge limits. Due to its advantage such as high efficiency, the adsorption process is a widely used successful technique for heavy metals removal from an aqueous solutions. On the other hand, determining the adsorption efficiencies of different adsorbents experimentally is both costly, and time-consuming considering that there are large number of process variables. Therefore, ANN can be used to make theoretical predictions with high efficiency in this treatment process. In this study, modeling of Pb2 removal from an aqueous solution by using biochars that produced by pyrolyzing of hazelnut, and walnut shell was studied at different adsorption conditions; pH 2.5-5, temperature 25-45oC, initial Pb2 concentration 15-45 mgL, adsorbent amount 1-3 gL, and mixing speed 200-600 rpm. The purpose of modeling studies with ANN approach was to estimate lead ions removal  as an output. Inputs for ANN modeling approach were selected as pH, initial Pb2 concentration, temperature, adsorbent dosage, and mixing speed. Experimental data were categorized 50:25:25 for two adsorption systems. Levenberg-Marquardt LM was preferred as a training function, and tansig was used as an activation function. The number of hidden neurons in the hidden layer was found by trial, and error. Values of correlation coefficient R2, and Mean Square Error MSE were taken to be performance criteria of the ANN modeling. R2 values were found to be 97, and 98 for biochars derived from walnut, and hazelnut shells, respectively. Results showed that ANN is an effective tool for modeling of adsorption system for the removal of lead ions from an aqueous solution. Additionally, different training algorithms such as Bayesian Regularization BR, and Scaled Conjugate Gradient SCG were used to compare the prediction capability.

 Lead Pb2 which is one of the most important heavy metals found in water sources, has a toxic effect on living things in aquatic environment. Therefore, the removal of Pb2 ions from wastewater is very important if its concentration is above the determined discharge limits. Due to its advantage such as high efficiency, the adsorption process is a widely used successful technique for heavy metals removal from an aqueous solutions. On the other hand, determining the adsorption efficiencies of different adsorbents experimentally is both costly, and time-consuming considering that there are large number of process variables. Therefore, ANN can be used to make theoretical predictions with high efficiency in this treatment process. In this study, modeling of Pb2 removal from an aqueous solution by using biochars that produced by pyrolyzing of hazelnut, and walnut shell was studied at different adsorption conditions; pH 2.5-5, temperature 25-45oC, initial Pb2 concentration 15-45 mgL, adsorbent amount 1-3 gL, and mixing speed 200-600 rpm. The purpose of modeling studies with ANN approach was to estimate lead ions removal  as an output. Inputs for ANN modeling approach were selected as pH, initial Pb2 concentration, temperature, adsorbent dosage, and mixing speed. Experimental data were categorized 50:25:25 for two adsorption systems. Levenberg-Marquardt LM was preferred as a training function, and tansig was used as an activation function. The number of hidden neurons in the hidden layer was found by trial, and error. Values of correlation coefficient R2, and Mean Square Error MSE were taken to be performance criteria of the ANN modeling. R2 values were found to be 97, and 98 for biochars derived from walnut, and hazelnut shells, respectively. Results showed that ANN is an effective tool for modeling of adsorption system for the removal of lead ions from an aqueous solution. Additionally, different training algorithms such as Bayesian Regularization BR, and Scaled Conjugate Gradient SCG were used to compare the prediction capability.

 Lead Pb2 which is one of the most important heavy metals found in water sources, has a toxic effect on living things in aquatic environment. Therefore, the removal of Pb2 ions from wastewater is very important if its concentration is above the determined discharge limits. Due to its advantage such as high efficiency, the adsorption process is a widely used successful technique for heavy metals removal from an aqueous solutions. On the other hand, determining the adsorption efficiencies of different adsorbents experimentally is both costly, and time-consuming considering that there are large number of process variables. Therefore, ANN can be used to make theoretical predictions with high efficiency in this treatment process. In this study, modeling of Pb2 removal from an aqueous solution by using biochars that produced by pyrolyzing of hazelnut, and walnut shell was studied at different adsorption conditions; pH 2.5-5, temperature 25-45oC, initial Pb2 concentration 15-45 mgL, adsorbent amount 1-3 gL, and mixing speed 200-600 rpm. The purpose of modeling studies with ANN approach was to estimate lead ions removal  as an output. Inputs for ANN modeling approach were selected as pH, initial Pb2 concentration, temperature, adsorbent dosage, and mixing speed. Experimental data were categorized 50:25:25 for two adsorption systems. Levenberg-Marquardt LM was preferred as a training function, and tansig was used as an activation function. The number of hidden neurons in the hidden layer was found by trial, and error. Values of correlation coefficient R2, and Mean Square Error MSE were taken to be performance criteria of the ANN modeling. R2 values were found to be 97, and 98 for biochars derived from walnut, and hazelnut shells, respectively. Results showed that ANN is an effective tool for modeling of adsorption system for the removal of lead ions from an aqueous solution. Additionally, different training algorithms such as Bayesian Regularization BR, and Scaled Conjugate Gradient SCG were used to compare the prediction capability.

 Lead Pb2 which is one of the most important heavy metals found in water sources, has a toxic effect on living things in aquatic environment. Therefore, the removal of Pb2 ions from wastewater is very important if its concentration is above the determined discharge limits. Due to its advantage such as high efficiency, the adsorption process is a widely used successful technique for heavy metals removal from an aqueous solutions. On the other hand, determining the adsorption efficiencies of different adsorbents experimentally is both costly, and time-consuming considering that there are large number of process variables. Therefore, ANN can be used to make theoretical predictions with high efficiency in this treatment process. In this study, modeling of Pb2 removal from an aqueous solution by using biochars that produced by pyrolyzing of hazelnut, and walnut shell was studied at different adsorption conditions; pH 2.5-5, temperature 25-45oC, initial Pb2 concentration 15-45 mgL, adsorbent amount 1-3 gL, and mixing speed 200-600 rpm. The purpose of modeling studies with ANN approach was to estimate lead ions removal  as an output. Inputs for ANN modeling approach were selected as pH, initial Pb2 concentration, temperature, adsorbent dosage, and mixing speed. Experimental data were categorized 50:25:25 for two adsorption systems. Levenberg-Marquardt LM was preferred as a training function, and tansig was used as an activation function. The number of hidden neurons in the hidden layer was found by trial, and error. Values of correlation coefficient R2, and Mean Square Error MSE were taken to be performance criteria of the ANN modeling. R2 values were found to be 97, and 98 for biochars derived from walnut, and hazelnut shells, respectively. Results showed that ANN is an effective tool for modeling of adsorption system for the removal of lead ions from an aqueous solution. Additionally, different training algorithms such as Bayesian Regularization BR, and Scaled Conjugate Gradient SCG were used to compare the prediction capability.

Makale detayları

Artificial neural network approach for lead removal from aqueous solution by agricultural waste derived biochars

Yazarlar:

Nihan Kaya | Fatma Erdem

Yayıncı:

Yildiz Technical University

Ana Başlıklar:

Computer Software

Dergi:

Sigma Journal of Engineering and Natural Sciences Vol.41 Issue 1, pp.64-73

Belge Tipi:

Makale

Yayın Tarihi:

3/2023

Belge Dili:

İngilizce

Document ID (Org No.):

2001304941

pISSN:

1304-7191

Adsorption

Artificial Neural Network

Biochar

Lead Ions (Pb2+)

Modeling

Sayı

Makale detayları

Artificial neural network approach for lead removal from aqueous solution by agricultural waste derived biochars

Yazarlar: Nihan Kaya | Fatma Erdem

Yayıncı: Yildiz Technical University

Ana Başlıklar: Computer Software

Dergi: Sigma Journal of Engineering and Natural Sciences Vol.41 Issue 1, pp.64-73

Belge Tipi: Makale

Yayın Tarihi: 3/2023

Belge Dili: İngilizce

Document ID (Org No.): 2001304941

pISSN: 1304-7191

Adsorption

Artificial Neural Network

Biochar

Lead Ions (Pb2+)

Modeling

Sayı

Yazarlar:

Nihan Kaya | Fatma Erdem

Yayıncı:

Yildiz Technical University

Ana Başlıklar:

Computer Software

Dergi:

Sigma Journal of Engineering and Natural Sciences Vol.41 Issue 1, pp.64-73

Belge Tipi:

Makale

Yayın Tarihi:

3/2023

Belge Dili:

İngilizce

Document ID (Org No.):

2001304941

pISSN:

1304-7191