mer-[InCl3(C5D5N)3]2·C5D5N: A New d5-pyridine Derivative of Indium(III) Chloride Complex

Ali Tuna; Anastassios Papageorgiou; Anssi Peuronen; Pekka Peljo; Günther Knör

Makale detayları

mer-[InCl3(C5D5N)3]2·C5D5N: A New d5-pyridine Derivative of Indium(III) Chloride Complex

Yazarlar:

Ali Tuna | Anastassios Papageorgiou | Anssi Peuronen | Pekka Peljo | Günther Knör

Yayıncı:

Turkish Chemical Society

Ana Başlıklar:

Main Group Metal Chemistry

Dergi:

Journal of the Turkish Chemical Society Section A: Chemistry Vol.12 Issue 1, pp.15-22

Belge Tipi:

Makale

Yayın Tarihi:

3/2025

Belge Dili:

İngilizce

Document ID (Org No.):

2001340695

pISSN:

2149-0120

Anahtar kelimeler:

Özet:

 In this study, we report the crystal structure of a meridional octahedral pyridine-indiumIII chloride adduct, mer-trichlorotrisd5-pyridineindiumIII0.5d5-pyridine, InCl3C5D5N30.5C5D5N, which exhibits an unreported molecule-to-solvent ratio compared to other substituted and unsubstituted pyridine-indiumIII chloride adducts described in earlier literature. The bonding characteristics of this d5-pyridine complex are compared to analogous complexes that have already been reported. Furthermore, the role of this metal complex in indium insertion into corrole ligands is discussed.

 In this study, we report the crystal structure of a meridional octahedral pyridine-indiumIII chloride adduct, mer-trichlorotrisd5-pyridineindiumIII0.5d5-pyridine, InCl3C5D5N30.5C5D5N, which exhibits an unreported molecule-to-solvent ratio compared to other substituted and unsubstituted pyridine-indiumIII chloride adducts described in earlier literature. The bonding characteristics of this d5-pyridine complex are compared to analogous complexes that have already been reported. Furthermore, the role of this metal complex in indium insertion into corrole ligands is discussed.

 In this study, we report the crystal structure of a meridional octahedral pyridine-indiumIII chloride adduct, mer-trichlorotrisd5-pyridineindiumIII0.5d5-pyridine, InCl3C5D5N30.5C5D5N, which exhibits an unreported molecule-to-solvent ratio compared to other substituted and unsubstituted pyridine-indiumIII chloride adducts described in earlier literature. The bonding characteristics of this d5-pyridine complex are compared to analogous complexes that have already been reported. Furthermore, the role of this metal complex in indium insertion into corrole ligands is discussed.

 In this study, we report the crystal structure of a meridional octahedral pyridine-indiumIII chloride adduct, mer-trichlorotrisd5-pyridineindiumIII0.5d5-pyridine, InCl3C5D5N30.5C5D5N, which exhibits an unreported molecule-to-solvent ratio compared to other substituted and unsubstituted pyridine-indiumIII chloride adducts described in earlier literature. The bonding characteristics of this d5-pyridine complex are compared to analogous complexes that have already been reported. Furthermore, the role of this metal complex in indium insertion into corrole ligands is discussed.

Makale detayları

mer-[InCl3(C5D5N)3]2·C5D5N: A New d5-pyridine Derivative of Indium(III) Chloride Complex

Yazarlar:

Ali Tuna | Anastassios Papageorgiou | Anssi Peuronen | Pekka Peljo | Günther Knör

Yayıncı:

Turkish Chemical Society

Ana Başlıklar:

Main Group Metal Chemistry

Dergi:

Journal of the Turkish Chemical Society Section A: Chemistry Vol.12 Issue 1, pp.15-22

Belge Tipi:

Makale

Yayın Tarihi:

3/2025

Belge Dili:

İngilizce

Document ID (Org No.):

2001340695

pISSN:

2149-0120

indium

d5-pyridine

mer-isomer

solvated-complex

indium corrole

Sayı

Makale detayları

mer-[InCl3(C5D5N)3]2·C5D5N: A New d5-pyridine Derivative of Indium(III) Chloride Complex

Yazarlar: Ali Tuna | Anastassios Papageorgiou | Anssi Peuronen | Pekka Peljo | Günther Knör

Yayıncı: Turkish Chemical Society

Ana Başlıklar: Main Group Metal Chemistry

Dergi: Journal of the Turkish Chemical Society Section A: Chemistry Vol.12 Issue 1, pp.15-22

Belge Tipi: Makale

Yayın Tarihi: 3/2025

Belge Dili: İngilizce

Document ID (Org No.): 2001340695

pISSN: 2149-0120

indium

d5-pyridine

mer-isomer

solvated-complex

indium corrole

Sayı

Yazarlar:

Ali Tuna | Anastassios Papageorgiou | Anssi Peuronen | Pekka Peljo | Günther Knör

Yayıncı:

Turkish Chemical Society

Ana Başlıklar:

Main Group Metal Chemistry

Dergi:

Journal of the Turkish Chemical Society Section A: Chemistry Vol.12 Issue 1, pp.15-22

Belge Tipi:

Makale

Yayın Tarihi:

3/2025

Belge Dili:

İngilizce

Document ID (Org No.):

2001340695

pISSN:

2149-0120