Thermokinetic and Structural Shape Memory Effect Characteristics of Novel Quaternary CuAlNiCr HTSMA

Oktay Karaduman; İskender Özkul; Gökhan İstek; Canan Aksu Canbay

Makale detayları

Thermokinetic and Structural Shape Memory Effect Characteristics of Novel Quaternary CuAlNiCr HTSMA

Yazarlar:

Oktay Karaduman | İskender Özkul | Gökhan İstek | Canan Aksu Canbay

Yayıncı:

Fırat University

Ana Başlıklar:

Malzeme Fiziği | Termodinamik ve İstatistiksel Fizik

Dergi:

Fırat Üniversitesi Fen Bilimleri Dergisi Vol.36 Issue 1, pp.25-34

Belge Tipi:

Makale

Yayın Tarihi:

3/2024

Belge Dili:

İngilizce

Document ID (Org No.):

2001314435

pISSN:

1308-9064

Anahtar kelimeler:

Özet:

 CuAlNi shape memory alloys SMAs are one of the most prominent Cu-based SMAs mainly due to their shape memory properties at high temperatures. Therefore, they are interested in high temperature SMA applications. Their good thermal stability but brittleness originated from their coarse grain size are their other pros and cons. In this study, the low-cost quaternary CuAlNiCr high-temperature SMA HTSMA with a new unprecedented chemical composition including trace amount of chromium element was fabricated by arc melting technique. After arc melting process, traditional homogenization of small alloy samples in the high β-phase temperature region and quenching them in iced-brine water were proceeded. To characterize the shape memory effect property of the alloy, differential calorimetry and microstructural X-ray diffraction XRD tests were carried out. The cyclic DSC differential scanning calorimetry tests carried out at various heatingcooling rates showed the splendid endothermic and exothermic peaks of reversible martensitic phase transformations in the temperature range between around 150-220 C, thence the produced alloy is qualified as a high-temperature SMA. Using DSC peak analysis data, the finish and start temperatures of every martensitic phase transition, hysteresis gap, plus some other important thermodynamic parameters values were also determined. Among them, the high enthalpy change amounts occurred during the transformations implied the good shape memory effect feature of the alloy. A DTA differential thermal calorimetry test taken at only one heatingcooling rate revealed both the reversible martensitic transformation peaks and the other phase transition peaks at higher temperatures. The consecutive phase transition step peaks of β1 B1L21B2A2 on the heating-part of the DTA thermogram curve of the alloy were observed as similar to those seen in the other Cu-based shape memory alloys. Furthermore, at room temperature, the presence and types of the martensite phases formed in the alloy were revealed by the XRD pattern of the alloy obtained by using CuKα radiation. The results showed that the novel CuAlNiCr high-temperature SMA can be useful in the high-temperature SMA applications.

 CuAlNi shape memory alloys SMAs are one of the most prominent Cu-based SMAs mainly due to their shape memory properties at high temperatures. Therefore, they are interested in high temperature SMA applications. Their good thermal stability but brittleness originated from their coarse grain size are their other pros and cons. In this study, the low-cost quaternary CuAlNiCr high-temperature SMA HTSMA with a new unprecedented chemical composition including trace amount of chromium element was fabricated by arc melting technique. After arc melting process, traditional homogenization of small alloy samples in the high β-phase temperature region and quenching them in iced-brine water were proceeded. To characterize the shape memory effect property of the alloy, differential calorimetry and microstructural X-ray diffraction XRD tests were carried out. The cyclic DSC differential scanning calorimetry tests carried out at various heatingcooling rates showed the splendid endothermic and exothermic peaks of reversible martensitic phase transformations in the temperature range between around 150-220 C, thence the produced alloy is qualified as a high-temperature SMA. Using DSC peak analysis data, the finish and start temperatures of every martensitic phase transition, hysteresis gap, plus some other important thermodynamic parameters values were also determined. Among them, the high enthalpy change amounts occurred during the transformations implied the good shape memory effect feature of the alloy. A DTA differential thermal calorimetry test taken at only one heatingcooling rate revealed both the reversible martensitic transformation peaks and the other phase transition peaks at higher temperatures. The consecutive phase transition step peaks of β1 B1L21B2A2 on the heating-part of the DTA thermogram curve of the alloy were observed as similar to those seen in the other Cu-based shape memory alloys. Furthermore, at room temperature, the presence and types of the martensite phases formed in the alloy were revealed by the XRD pattern of the alloy obtained by using CuKα radiation. The results showed that the novel CuAlNiCr high-temperature SMA can be useful in the high-temperature SMA applications.

 CuAlNi shape memory alloys SMAs are one of the most prominent Cu-based SMAs mainly due to their shape memory properties at high temperatures. Therefore, they are interested in high temperature SMA applications. Their good thermal stability but brittleness originated from their coarse grain size are their other pros and cons. In this study, the low-cost quaternary CuAlNiCr high-temperature SMA HTSMA with a new unprecedented chemical composition including trace amount of chromium element was fabricated by arc melting technique. After arc melting process, traditional homogenization of small alloy samples in the high β-phase temperature region and quenching them in iced-brine water were proceeded. To characterize the shape memory effect property of the alloy, differential calorimetry and microstructural X-ray diffraction XRD tests were carried out. The cyclic DSC differential scanning calorimetry tests carried out at various heatingcooling rates showed the splendid endothermic and exothermic peaks of reversible martensitic phase transformations in the temperature range between around 150-220 C, thence the produced alloy is qualified as a high-temperature SMA. Using DSC peak analysis data, the finish and start temperatures of every martensitic phase transition, hysteresis gap, plus some other important thermodynamic parameters values were also determined. Among them, the high enthalpy change amounts occurred during the transformations implied the good shape memory effect feature of the alloy. A DTA differential thermal calorimetry test taken at only one heatingcooling rate revealed both the reversible martensitic transformation peaks and the other phase transition peaks at higher temperatures. The consecutive phase transition step peaks of β1 B1L21B2A2 on the heating-part of the DTA thermogram curve of the alloy were observed as similar to those seen in the other Cu-based shape memory alloys. Furthermore, at room temperature, the presence and types of the martensite phases formed in the alloy were revealed by the XRD pattern of the alloy obtained by using CuKα radiation. The results showed that the novel CuAlNiCr high-temperature SMA can be useful in the high-temperature SMA applications.

 CuAlNi şekil hafızalı alaşımlar ŞHAlar, esas olarak yüksek sıcaklıklardaki şekil hafızalı özelliklerinden dolayı en öne çıkan Cu-bazlı ŞHAlardandır. Bu ŞHAlara bu nedenle yüksek sıcaklık ŞHA uygulamalarında ilgi duyulmaktadır. İyi termal kararlılıkları ancak iri tane boyutlarından kaynaklanan kırılganlıkları diğer artıları ve eksileridir. Bu çalışmada, eser miktarda krom elementi içeren benzersiz bir kimyasal bileşime sahip dörtlü CuAlNiCr yüksek sıcaklık ŞHA YSŞHA, ark eritme tekniği ile üretildi. Ark eritme işleminden sonra, küçük alaşım numunelerinin yüksek β fazı sıcaklık bölgesinde geleneksel homojenleştirilip tuzlu buzlu suda hızlıca soğutuldu. Alaşımın şekil hafıza etkisi özelliğini karakterize etmek için diferansiyel kalorimetri ve mikroyapısal X-ışını kırınımı XRD testleri gerçekleştirildi. Farklı ısıtmasoğutma hızlarında gerçekleştirilen diferansiyel taramalı kalorimetri DSC testleri, yaklaşık 150-220 C arasındaki sıcaklık aralığında tersinir martensitik faz dönüşümlerinin olağanüstü ekzotermik ve endotermik piklerini gösterdi; bundan dolayı üretilen alaşım bir yüksek sıcaklık ŞHA olarak sınıflandırıldı. DSC pik analizi verileri kullanılarak her bir martensitik faz dönüşümünün başlangıç ve bitiş sıcaklıkları, histeresiz aralığı ve diğer bazı önemli termodinamik parametreleri belirlendi. Bunlar arasında, dönüşümler sırasında meydana gelen yüksek entalpi değişim miktarları, alaşımın iyi şekil hafıza etkisi özelliğine sahip olduğuna işaret etmiştir. Tek bir ısıtmasoğutma hızında daha yüksek sıcaklıklara kadar çıkılarak yapılan diferansiyel termal kalorimetri DTA testi, hem tersinir martensitik dönüşüm piklerini yine ve hem de diğer faz geçiş piklerinin oluştuğunu gösterdi. Alaşımın DTA eğrisinin ısınma kısmında β1B1L21B2A2 ardışık faz geçiş adımı pikleri diğer Cu bazlı şekil hafızalı alaşımlarda görülenlere benzer şekilde gözlendi. Ayrıca oda sıcaklığında alaşımda oluşan martensit fazların varlığı, alaşımın CuKα radyasyonu kullanılarak elde edilen XRD deseni ile ortaya çıkarılmıştır. Sonuçlar, yeni CuAlNiCr yüksek sıcaklık ŞHAsının yüksek sıcaklık ŞHA uygulamalarında faydalı olabileceğini gösterdi.

Makale detayları

Thermokinetic and Structural Shape Memory Effect Characteristics of Novel Quaternary CuAlNiCr HTSMA

Yazarlar:

Oktay Karaduman | İskender Özkul | Gökhan İstek | Canan Aksu Canbay

Yayıncı:

Fırat University

Ana Başlıklar:

Malzeme Fiziği | Termodinamik ve İstatistiksel Fizik

Dergi:

Fırat Üniversitesi Fen Bilimleri Dergisi Vol.36 Issue 1, pp.25-34

Belge Tipi:

Makale

Yayın Tarihi:

3/2024

Belge Dili:

İngilizce

Document ID (Org No.):

2001314435

pISSN:

1308-9064

High-temperature shape memory alloy

CuAlNiCr

martensitic transformation

DSC

DTAYüksek sıcaklık şekil hafızalı alaşım

CuAlNiCr

martensitik dönüşüm

DSC

DTA

Sayı

Makale detayları

Yazarlar: Oktay Karaduman | İskender Özkul | Gökhan İstek | Canan Aksu Canbay

Yayıncı: Fırat University

Ana Başlıklar: Malzeme Fiziği | Termodinamik ve İstatistiksel Fizik

Dergi: Fırat Üniversitesi Fen Bilimleri Dergisi Vol.36 Issue 1, pp.25-34

Belge Tipi: Makale

Yayın Tarihi: 3/2024

Belge Dili: İngilizce

Document ID (Org No.): 2001314435

pISSN: 1308-9064

Sayı

Yazarlar:

Oktay Karaduman | İskender Özkul | Gökhan İstek | Canan Aksu Canbay

Yayıncı:

Fırat University

Ana Başlıklar:

Malzeme Fiziği | Termodinamik ve İstatistiksel Fizik

Dergi:

Fırat Üniversitesi Fen Bilimleri Dergisi Vol.36 Issue 1, pp.25-34

Belge Tipi:

Makale

Yayın Tarihi:

3/2024

Belge Dili:

İngilizce

Document ID (Org No.):

2001314435

pISSN:

1308-9064