Separation and preconcentration of lead(II), cobalt(II), and nickel(II) on EDTA immobilized activated carbon cloth prior to flame atomic absorption spectrometric determination in environmental samples

ZEID ABDULLAH ALOTHMAN; ERKAN YILMAZ; MOHAMED HABİLA; MUSTAFA SOYLAK

Makale detayları

Separation and preconcentration of lead(II), cobalt(II), and nickel(II) on EDTA immobilized activated carbon cloth prior to flame atomic absorption spectrometric determination in environmental samples

Yazarlar:

ZEID ABDULLAH ALOTHMAN | ERKAN YILMAZ | MOHAMED HABİLA | MUSTAFA SOYLAK

Yayıncı:

TUBITAK

Ana Başlıklar:

Uygulamalı fizik

Dergi:

Turkish Journal of Chemistry 2015 Vol.39 Issue 5, pp.1038-1049

Belge Tipi:

Makale

Yayın Tarihi:

12/2015

Belge Dili:

İngilizce

Document ID (Org No.):

2000726781

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527

Özet:

 

The synthesis and characterization of ethylenediaminetetraacetic acid immobilized activated carbon cloth was performed in the present work. It was used for preconcentration-separation of lead(II), cobalt(II), and nickel(II) at trace levels as an adsorbent. Factors including pH, concentration and volume of eluent, sample and eluent flow rates, sample volume, and effect of coexisting ions on the solid phase extraction of analytes were examined. The preconcentration factor was 50. The detection limits for Pb(II), Co(II), and Ni(II) were 4.39, 0.99 and 0.91 μμ\mu g L−1−1^{-1}, respectively. The adsorption capacity for Pb(II), Co(II), and Ni(II) ions was found as 11.0, 11.2, and 10.2 mg g−1−1^{-1}, respectively. The validation of the method was performed by the analysis of certified reference materials (SPS-WW2 wastewater and BCR-146R sewage sludge amended soil (industrial origin)). The method was successfully applied for the determination of lead, cobalt, and nickel in fertilizer and water samples from Kayseri, Turkey.

 

The synthesis and characterization of ethylenediaminetetraacetic acid immobilized activated carbon cloth was performed in the present work. It was used for preconcentration-separation of lead(II), cobalt(II), and nickel(II) at trace levels as an adsorbent. Factors including pH, concentration and volume of eluent, sample and eluent flow rates, sample volume, and effect of coexisting ions on the solid phase extraction of analytes were examined. The preconcentration factor was 50. The detection limits for Pb(II), Co(II), and Ni(II) were 4.39, 0.99 and 0.91 μμ\mu g L−1−1^{-1}, respectively. The adsorption capacity for Pb(II), Co(II), and Ni(II) ions was found as 11.0, 11.2, and 10.2 mg g−1−1^{-1}, respectively. The validation of the method was performed by the analysis of certified reference materials (SPS-WW2 wastewater and BCR-146R sewage sludge amended soil (industrial origin)). The method was successfully applied for the determination of lead, cobalt, and nickel in fertilizer and water samples from Kayseri, Turkey.

Makale detayları

Separation and preconcentration of lead(II), cobalt(II), and nickel(II) on EDTA immobilized activated carbon cloth prior to flame atomic absorption spectrometric determination in environmental samples

Yazarlar: ZEID ABDULLAH ALOTHMAN | ERKAN YILMAZ | MOHAMED HABİLA | MUSTAFA SOYLAK

Yayıncı: TUBITAK

Ana Başlıklar: Uygulamalı fizik

Dergi: Turkish Journal of Chemistry 2015 Vol.39 Issue 5, pp.1038-1049

Belge Tipi: Makale

Yayın Tarihi: 12/2015

Belge Dili: İngilizce

Document ID (Org No.): 2000726781

Sıklık: İki Aylık

eISSN: 1303-6130

pISSN: 1300-0527

Sayı

Yazarlar:

ZEID ABDULLAH ALOTHMAN | ERKAN YILMAZ | MOHAMED HABİLA | MUSTAFA SOYLAK

Yayıncı:

TUBITAK

Ana Başlıklar:

Uygulamalı fizik

Dergi:

Turkish Journal of Chemistry 2015 Vol.39 Issue 5, pp.1038-1049

Belge Tipi:

Makale

Yayın Tarihi:

12/2015

Belge Dili:

İngilizce

Document ID (Org No.):

2000726781

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527