pH effect on hydrothermal synthesis of the coordination polymers containing pyrazine-2,3-dicarboxylate: Investigation of thermal stability, luminescence and electrical conductivity properties

Burak AY; Emel YILDIZ; Jon ZUBİETA

doi:https://doi.org/10.18596/jotcsa.565700

Makale detayları

pH effect on hydrothermal synthesis of the coordination polymers containing pyrazine-2,3-dicarboxylate: Investigation of thermal stability, luminescence and electrical conductivity properties

Yazarlar:

Burak AY | Emel YILDIZ | Jon ZUBİETA

Yayıncı:

Turkish Chemical Society

Ana Başlıklar:

İnorganik kimya

Dergi:

Journal of the Turkish Chemical Society Section A: Chemistry 2020 Vol.7 Issue 1, pp.243-258

Belge Tipi:

Makale

Yayın Tarihi:

2/2020

Belge Dili:

İngilizce

Document ID (Org No.):

2000502724

Sıklık:

Üç Aylık

eISSN:

2149-0120

DOI:

https://doi.org/10.18596/jotcsa.565700

Özet:

 

Hydrothermal reactions of lanthanide(III) salt with
2,3-pyrazinedicarboxylic (2,3-pzdc) acid yielded the coordination polymers [La2(2,3-pzdc)3(H2O)]n.3nH2O
(1) and [La2(2,3-pzdc)3(H2O)]n.2nH2O
(2). 
Compounds
were obtained in a three dimensional form with different pH values under
subcritical water conditions. The structures had variable coordination numbers. In addition, pH values play an important role in
the structural chemistry of these materials. Different characterization techniques (Elemental
analysis, FT-IR, ICP-OES, TG/DTA, FESEM, PXRD, BET and single crystal X-ray)
were carried out to confirm crystallinity, porosity, purity and chemical
composition of the coordination polymers. Crystal structures of the polymers were
examined in detail. Their thermal stability, luminescence and electrical
conductivity properties were investigated in the solid state.

Makale detayları

pH effect on hydrothermal synthesis of the coordination polymers containing pyrazine-2,3-dicarboxylate: Investigation of thermal stability, luminescence and electrical conductivity properties

Yazarlar: Burak AY | Emel YILDIZ | Jon ZUBİETA

Yayıncı: Turkish Chemical Society

Ana Başlıklar: İnorganik kimya

Dergi: Journal of the Turkish Chemical Society Section A: Chemistry 2020 Vol.7 Issue 1, pp.243-258

Belge Tipi: Makale

Yayın Tarihi: 2/2020

Belge Dili: İngilizce

Document ID (Org No.): 2000502724

Sıklık: Üç Aylık

eISSN: 2149-0120

DOI: https://doi.org/10.18596/jotcsa.565700

Sayı

Yazarlar:

Burak AY | Emel YILDIZ | Jon ZUBİETA

Yayıncı:

Turkish Chemical Society

Ana Başlıklar:

İnorganik kimya

Dergi:

Journal of the Turkish Chemical Society Section A: Chemistry 2020 Vol.7 Issue 1, pp.243-258

Belge Tipi:

Makale

Yayın Tarihi:

2/2020

Belge Dili:

İngilizce

Document ID (Org No.):

2000502724

Sıklık:

Üç Aylık

eISSN:

2149-0120

DOI:

https://doi.org/10.18596/jotcsa.565700