The Spectroscopic and Thermal Properties, Antimicrobial Activities and DNA Interactions of 4-(Fluorobenzyl)Spiro(N/O) Cyclotriphosphazenium Salts

Gamze ELMAS; Aytuğ OKUMUŞ; Zeynel Kılıç; Süheyla Pınar Çelik; Leyla Açık

doi:https://doi.org/10.18596/jotcsa.316902

Makale detayları

The Spectroscopic and Thermal Properties, Antimicrobial Activities and DNA Interactions of 4-(Fluorobenzyl)Spiro(N/O) Cyclotriphosphazenium Salts

Yazarlar:

Gamze ELMAS | Aytuğ OKUMUŞ | Zeynel Kılıç | Süheyla Pınar Çelik | Leyla Açık

Yayıncı:

Turkish Chemical Society

Ana Başlıklar:

Kimya mühendisliği | Uygulamalı fizik

Dergi:

Journal of the Turkish Chemical Society Section A: Chemistry 2017 Vol.4 Issue 3, pp.993-1016

Belge Tipi:

Makale

Yayın Tarihi:

9/2017

Belge Dili:

Türkçe

Document ID (Org No.):

2000503531

Sıklık:

Üç Aylık

eISSN:

2149-0120

DOI:

https://doi.org/10.18596/jotcsa.316902

Özet:

 


The protic
ionic liquids (PILs) (3a-3d) were
synthesized from the reactions of tetraamino-4-(fluorobenzyl)spiro(N/O)cyclotriphosphazenes (2a-2d) with the gentisic acid in THF. The
structures of the PILs were verified by elemental analyses, Fourier transform infrared (FTIR), 1H, 13C
{1H} and 31P {1H} NMR techniques. The thermal properties of the PILs were
evaluated using TG/DTG/DTA instrument.
On the other hand, the antimicrobial activities of the PILs were examined
against some bacteria and fungi, and the obtained results were compared with
the evaluations of the corresponding fully substituted cyclotriphosphazene
bases. The interactions between the PILs and supercoiled PBR322 DNA were also scrutinized,
and it was determined that they exhibited significant
conformational changes.


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Makale detayları

The Spectroscopic and Thermal Properties, Antimicrobial Activities and DNA Interactions of 4-(Fluorobenzyl)Spiro(N/O) Cyclotriphosphazenium Salts

Yazarlar: Gamze ELMAS | Aytuğ OKUMUŞ | Zeynel Kılıç | Süheyla Pınar Çelik | Leyla Açık

Yayıncı: Turkish Chemical Society

Ana Başlıklar: Kimya mühendisliği | Uygulamalı fizik

Dergi: Journal of the Turkish Chemical Society Section A: Chemistry 2017 Vol.4 Issue 3, pp.993-1016

Belge Tipi: Makale

Yayın Tarihi: 9/2017

Belge Dili: Türkçe

Document ID (Org No.): 2000503531

Sıklık: Üç Aylık

eISSN: 2149-0120

DOI: https://doi.org/10.18596/jotcsa.316902

Sayı

Yazarlar:

Gamze ELMAS | Aytuğ OKUMUŞ | Zeynel Kılıç | Süheyla Pınar Çelik | Leyla Açık

Yayıncı:

Turkish Chemical Society

Ana Başlıklar:

Kimya mühendisliği | Uygulamalı fizik

Dergi:

Journal of the Turkish Chemical Society Section A: Chemistry 2017 Vol.4 Issue 3, pp.993-1016

Belge Tipi:

Makale

Yayın Tarihi:

9/2017

Belge Dili:

Türkçe

Document ID (Org No.):

2000503531

Sıklık:

Üç Aylık

eISSN:

2149-0120

DOI:

https://doi.org/10.18596/jotcsa.316902