Synthesis and characterization of substituted benzimidazole Co(II), Fe(II), and Zn(II) complexes and structural characterization of dichlorobis{1-[2-(1-piperidinyl)ethyl]-1H-benzimidazole-K N3} zinc(II)

Hasan KÜÇÜKBAY; Ülkü YILMAZ; Mehmet AKKURT; Orhan BÜYÜKGÜNGÖR

doi:https://doi.org/10.3906/kim-1405-47

Makale detayları

Synthesis and characterization of substituted benzimidazole Co(II), Fe(II), and Zn(II) complexes and structural characterization of dichlorobis{1-[2-(1-piperidinyl)ethyl]-1H-benzimidazole-K N3} zinc(II)

Yazarlar:

Hasan KÜÇÜKBAY | Ülkü YILMAZ | Mehmet AKKURT | Orhan BÜYÜKGÜNGÖR

Yayıncı:

TUBITAK

Ana Başlıklar:

Uygulamalı fizik

Dergi:

Turkish Journal of Chemistry 2015 Vol.39 Issue 1, pp.108-120

Belge Tipi:

Makale

Yayın Tarihi:

3/2015

Belge Dili:

İngilizce

Document ID (Org No.):

2000726973

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527

DOI:

https://doi.org/10.3906/kim-1405-47

Özet:

 

The Co(II), Fe(II), and Zn(II) complexes of 1-(3-phenyl)propylbenzimidazole  (PPBI), 5-nitro-1-(3-phenyl) propylbenzimidazole (PPNBI),  1-[2-(4-morpholinyl)ethyl]benzimidazole (MEBI),  1-[2-(1-piperidinyl)ethyl]benzimidazole (PEBI), and  5-nitro-1-[2-(1-piperidinyl)ethyl]benzimidazole (PENBI) were synthesized and  characterized by 1H NMR, 13C NMR, and elemental analyses. The  magnitudes of the magnetic moments for paramagnetic complexes were between  4.07 and 5.11 B.M. Moreover, the crystal structure of  dichlorobis{1-[2-(1-piperidinyl)ethyl]-1H-benzimidazole-KN3}  zinc(II) was determined by single crystal X-ray diffraction.

 

The Co(II), Fe(II), and Zn(II) complexes of 1-(3-phenyl)propylbenzimidazole  (PPBI), 5-nitro-1-(3-phenyl) propylbenzimidazole (PPNBI),  1-[2-(4-morpholinyl)ethyl]benzimidazole (MEBI),  1-[2-(1-piperidinyl)ethyl]benzimidazole (PEBI), and  5-nitro-1-[2-(1-piperidinyl)ethyl]benzimidazole (PENBI) were synthesized and  characterized by 1H NMR, 13C NMR, and elemental analyses. The  magnitudes of the magnetic moments for paramagnetic complexes were between  4.07 and 5.11 B.M. Moreover, the crystal structure of  dichlorobis{1-[2-(1-piperidinyl)ethyl]-1H-benzimidazole-KN3}  zinc(II) was determined by single crystal X-ray diffraction.

Makale detayları

Synthesis and characterization of substituted benzimidazole Co(II), Fe(II), and Zn(II) complexes and structural characterization of dichlorobis{1-[2-(1-piperidinyl)ethyl]-1H-benzimidazole-K N3} zinc(II)

Yazarlar: Hasan KÜÇÜKBAY | Ülkü YILMAZ | Mehmet AKKURT | Orhan BÜYÜKGÜNGÖR

Yayıncı: TUBITAK

Ana Başlıklar: Uygulamalı fizik

Dergi: Turkish Journal of Chemistry 2015 Vol.39 Issue 1, pp.108-120

Belge Tipi: Makale

Yayın Tarihi: 3/2015

Belge Dili: İngilizce

Document ID (Org No.): 2000726973

Sıklık: İki Aylık

eISSN: 1303-6130

pISSN: 1300-0527

DOI: https://doi.org/10.3906/kim-1405-47

Sayı

Yazarlar:

Hasan KÜÇÜKBAY | Ülkü YILMAZ | Mehmet AKKURT | Orhan BÜYÜKGÜNGÖR

Yayıncı:

TUBITAK

Ana Başlıklar:

Uygulamalı fizik

Dergi:

Turkish Journal of Chemistry 2015 Vol.39 Issue 1, pp.108-120

Belge Tipi:

Makale

Yayın Tarihi:

3/2015

Belge Dili:

İngilizce

Document ID (Org No.):

2000726973

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527

DOI:

https://doi.org/10.3906/kim-1405-47