SYNTHESIS, CHARACTERIZATION, AND CHEMOSENSING APPLICATION OF POLY(METHYL METHACRYLATE-CO-HYDROXYETHYL METHACRYLATE) WITH DANSYL SIDE GROUP

Erdinç DOĞANCI; Mesut GORUR

doi:https://doi.org/10.18596/jotcsa.28202

Makale detayları

SYNTHESIS, CHARACTERIZATION, AND CHEMOSENSING APPLICATION OF POLY(METHYL METHACRYLATE-CO-HYDROXYETHYL METHACRYLATE) WITH DANSYL SIDE GROUP

Yazarlar:

Erdinç DOĞANCI | Mesut GORUR

Yayıncı:

Turkish Chemical Society

Ana Başlıklar:

Kimya mühendisliği

Dergi:

Journal of the Turkish Chemical Society Section A: Chemistry 2016 Vol.3 Issue 3, pp.565-582

Belge Tipi:

Makale

Yayın Tarihi:

1/2017

Belge Dili:

İngilizce

Document ID (Org No.):

2000503869

Sıklık:

Üç Aylık

eISSN:

2149-0120

DOI:

https://doi.org/10.18596/jotcsa.28202

Özet:

 


A novel dansyl side-functional polymer (P2) was prepared and employed as the metal cation sensing chemical probe. The synthesis of P2 was performed via free radical polymerization and esterification reactions in a two-step reaction sequence. P2 showed characteristic UV-vis and fluorescence emission bands for the dansyl unit. The fluorescence emission intensity of P2 gradually decreased as the concentrations of the added metal ions were increased. The highest quenching efficiencies (QE) were observed for Pb2+ (84.56%) and Co2+ (83.69%). Besides, the responses of P2 to the addition of Pb2+ cation were quite linear up to 50 equivalent. The presence of Cd2+, Hg2+, Mn2+, and Zn2+ cations did not pose significant interferences. Thus, P2 is a potential candidate for the fluorescence chemical sensor for Pb2+ cation.

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Makale detayları

SYNTHESIS, CHARACTERIZATION, AND CHEMOSENSING APPLICATION OF POLY(METHYL METHACRYLATE-CO-HYDROXYETHYL METHACRYLATE) WITH DANSYL SIDE GROUP

Yazarlar: Erdinç DOĞANCI | Mesut GORUR

Yayıncı: Turkish Chemical Society

Ana Başlıklar: Kimya mühendisliği

Dergi: Journal of the Turkish Chemical Society Section A: Chemistry 2016 Vol.3 Issue 3, pp.565-582

Belge Tipi: Makale

Yayın Tarihi: 1/2017

Belge Dili: İngilizce

Document ID (Org No.): 2000503869

Sıklık: Üç Aylık

eISSN: 2149-0120

DOI: https://doi.org/10.18596/jotcsa.28202

Sayı

Yazarlar:

Erdinç DOĞANCI | Mesut GORUR

Yayıncı:

Turkish Chemical Society

Ana Başlıklar:

Kimya mühendisliği

Dergi:

Journal of the Turkish Chemical Society Section A: Chemistry 2016 Vol.3 Issue 3, pp.565-582

Belge Tipi:

Makale

Yayın Tarihi:

1/2017

Belge Dili:

İngilizce

Document ID (Org No.):

2000503869

Sıklık:

Üç Aylık

eISSN:

2149-0120

DOI:

https://doi.org/10.18596/jotcsa.28202