Selective synthesis of cyclododec-2-en-1-yl ethers via palladium-catalyzed allylic substitution reaction: a kinetic study

Asen KOLEV; Magdalena MITKOVA; Stefan KOTOV; Encho BALBOLOV

Makale detayları

Selective synthesis of cyclododec-2-en-1-yl ethers via palladium-catalyzed allylic substitution reaction: a kinetic study

Yazarlar:

Asen KOLEV | Magdalena MITKOVA | Stefan KOTOV | Encho BALBOLOV

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Chemistry 2014 Vol.38 Issue 2, pp.242-247

Belge Tipi:

Makale

Yayın Tarihi:

5/2014

Belge Dili:

Türkçe

Document ID (Org No.):

2000727208

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527

Özet:

 

The palladium-catalyzed reaction between isomeric cyclododec-2-en-1-yl  acetates and primary aliphatic alcohols was found to result in high  yields of the reaction products obtained. The selectivity with respect to  cyclododec-2-en-1-yl ethers formed as reaction products ranged from 73%  to 93%. The kinetics of the reaction of acetoxycyclododec-2-enes with  alcohols was studied within the temperature range of 328--358 K. A kinetic  equation best fitting the experimental data was provided.

 

The palladium-catalyzed reaction between isomeric cyclododec-2-en-1-yl  acetates and primary aliphatic alcohols was found to result in high  yields of the reaction products obtained. The selectivity with respect to  cyclododec-2-en-1-yl ethers formed as reaction products ranged from 73%  to 93%. The kinetics of the reaction of acetoxycyclododec-2-enes with  alcohols was studied within the temperature range of 328--358 K. A kinetic  equation best fitting the experimental data was provided.

Makale detayları

Selective synthesis of cyclododec-2-en-1-yl ethers via palladium-catalyzed allylic substitution reaction: a kinetic study

Yazarlar: Asen KOLEV | Magdalena MITKOVA | Stefan KOTOV | Encho BALBOLOV

Yayıncı: TUBITAK

Dergi: Turkish Journal of Chemistry 2014 Vol.38 Issue 2, pp.242-247

Belge Tipi: Makale

Yayın Tarihi: 5/2014

Belge Dili: Türkçe

Document ID (Org No.): 2000727208

Sıklık: İki Aylık

eISSN: 1303-6130

pISSN: 1300-0527

Sayı

Yazarlar:

Asen KOLEV | Magdalena MITKOVA | Stefan KOTOV | Encho BALBOLOV

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Chemistry 2014 Vol.38 Issue 2, pp.242-247

Belge Tipi:

Makale

Yayın Tarihi:

5/2014

Belge Dili:

Türkçe

Document ID (Org No.):

2000727208

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527