Synthesis and Characterization of Schiff Base Compounds Containing Mono and Disulfonic Groups

İsmet Kaya; Feyza Kolcu; Sude Süel

Makale detayları

Synthesis and Characterization of Schiff Base Compounds Containing Mono and Disulfonic Groups

Yazarlar:

İsmet Kaya | Feyza Kolcu | Sude Süel

Yayıncı:

Manisa Celal Bayar University

Ana Başlıklar:

Malzeme Karekterizasyonu

Dergi:

Celal Bayar Üniversitesi Fen Bilimleri Dergisi Vol.20 Issue 4, pp.101-106

Belge Tipi:

Makale

Yayın Tarihi:

12/2024

Belge Dili:

İngilizce

Document ID (Org No.):

2001336641

pISSN:

1305-130X

Anahtar kelimeler:

Özet:

 Aromatic mono- or diamine compounds containing sulfonic groups are extensively utilized in the production of textiles, dyes, and polymers. Schiff base compounds are synthesized through the condensation reactions of these types of compounds with aromatic aldehydes or ketones. Due to their multifunctional nature, these Schiff base compounds serve as precursors in the synthesis of polyesters, polyethers, polyurethanes, and polyazomethines. The Schiff base compounds were 2,5-bisE-2-hydroxybenzylideneaminobenzene sulfonic acid SCH1 and 4,4-bisE-2-hydroxybenzylideneamino-1,1-biphenyl-2,2-disulfonic acid SCH2. The yields of SCH1 and SCH2 were calculated to be 85 and 80, respectively. Structural confirmation was achieved using FT-IR, UV-Vis, 1H NMR and 13C NMR measurements. Further characterization through fluorescence spectroscopy PL, thermogravimetric analysis TGA and cyclic voltammetry CV revealed high thermal stability of the compounds, attributed to the phenyl groups in their structures. TGA measurements indicated the initial decomposition temperatures for SCH1 and SCH2 at 298C and 347 C, respectively, with the residual masses of 34.64 and 41.24 at 1000 C.

 Aromatic mono- or diamine compounds containing sulfonic groups are extensively utilized in the production of textiles, dyes, and polymers. Schiff base compounds are synthesized through the condensation reactions of these types of compounds with aromatic aldehydes or ketones. Due to their multifunctional nature, these Schiff base compounds serve as precursors in the synthesis of polyesters, polyethers, polyurethanes, and polyazomethines. The Schiff base compounds were 2,5-bisE-2-hydroxybenzylideneaminobenzene sulfonic acid SCH1 and 4,4-bisE-2-hydroxybenzylideneamino-1,1-biphenyl-2,2-disulfonic acid SCH2. The yields of SCH1 and SCH2 were calculated to be 85 and 80, respectively. Structural confirmation was achieved using FT-IR, UV-Vis, 1H NMR and 13C NMR measurements. Further characterization through fluorescence spectroscopy PL, thermogravimetric analysis TGA and cyclic voltammetry CV revealed high thermal stability of the compounds, attributed to the phenyl groups in their structures. TGA measurements indicated the initial decomposition temperatures for SCH1 and SCH2 at 298C and 347 C, respectively, with the residual masses of 34.64 and 41.24 at 1000 C.

 Aromatic mono- or diamine compounds containing sulfonic groups are extensively utilized in the production of textiles, dyes, and polymers. Schiff base compounds are synthesized through the condensation reactions of these types of compounds with aromatic aldehydes or ketones. Due to their multifunctional nature, these Schiff base compounds serve as precursors in the synthesis of polyesters, polyethers, polyurethanes, and polyazomethines. The Schiff base compounds were 2,5-bisE-2-hydroxybenzylideneaminobenzene sulfonic acid SCH1 and 4,4-bisE-2-hydroxybenzylideneamino-1,1-biphenyl-2,2-disulfonic acid SCH2. The yields of SCH1 and SCH2 were calculated to be 85 and 80, respectively. Structural confirmation was achieved using FT-IR, UV-Vis, 1H NMR and 13C NMR measurements. Further characterization through fluorescence spectroscopy PL, thermogravimetric analysis TGA and cyclic voltammetry CV revealed high thermal stability of the compounds, attributed to the phenyl groups in their structures. TGA measurements indicated the initial decomposition temperatures for SCH1 and SCH2 at 298C and 347 C, respectively, with the residual masses of 34.64 and 41.24 at 1000 C.

 Aromatic mono- or diamine compounds containing sulfonic groups are extensively utilized in the production of textiles, dyes, and polymers. Schiff base compounds are synthesized through the condensation reactions of these types of compounds with aromatic aldehydes or ketones. Due to their multifunctional nature, these Schiff base compounds serve as precursors in the synthesis of polyesters, polyethers, polyurethanes, and polyazomethines. The Schiff base compounds were 2,5-bisE-2-hydroxybenzylideneaminobenzene sulfonic acid SCH1 and 4,4-bisE-2-hydroxybenzylideneamino-1,1-biphenyl-2,2-disulfonic acid SCH2. The yields of SCH1 and SCH2 were calculated to be 85 and 80, respectively. Structural confirmation was achieved using FT-IR, UV-Vis, 1H NMR and 13C NMR measurements. Further characterization through fluorescence spectroscopy PL, thermogravimetric analysis TGA and cyclic voltammetry CV revealed high thermal stability of the compounds, attributed to the phenyl groups in their structures. TGA measurements indicated the initial decomposition temperatures for SCH1 and SCH2 at 298C and 347 C, respectively, with the residual masses of 34.64 and 41.24 at 1000 C.

Makale detayları

Synthesis and Characterization of Schiff Base Compounds Containing Mono and Disulfonic Groups

Yazarlar:

İsmet Kaya | Feyza Kolcu | Sude Süel

Yayıncı:

Manisa Celal Bayar University

Ana Başlıklar:

Malzeme Karekterizasyonu

Dergi:

Celal Bayar Üniversitesi Fen Bilimleri Dergisi Vol.20 Issue 4, pp.101-106

Belge Tipi:

Makale

Yayın Tarihi:

12/2024

Belge Dili:

İngilizce

Document ID (Org No.):

2001336641

pISSN:

1305-130X

Schiff base

Sulfo Group

Thermal properties

Optical properties

LOI

Sayı

Makale detayları

Synthesis and Characterization of Schiff Base Compounds Containing Mono and Disulfonic Groups

Yazarlar: İsmet Kaya | Feyza Kolcu | Sude Süel

Yayıncı: Manisa Celal Bayar University

Ana Başlıklar: Malzeme Karekterizasyonu

Dergi: Celal Bayar Üniversitesi Fen Bilimleri Dergisi Vol.20 Issue 4, pp.101-106

Belge Tipi: Makale

Yayın Tarihi: 12/2024

Belge Dili: İngilizce

Document ID (Org No.): 2001336641

pISSN: 1305-130X

Schiff base

Sulfo Group

Thermal properties

Optical properties

LOI

Sayı

Yazarlar:

İsmet Kaya | Feyza Kolcu | Sude Süel

Yayıncı:

Manisa Celal Bayar University

Ana Başlıklar:

Malzeme Karekterizasyonu

Dergi:

Celal Bayar Üniversitesi Fen Bilimleri Dergisi Vol.20 Issue 4, pp.101-106

Belge Tipi:

Makale

Yayın Tarihi:

12/2024

Belge Dili:

İngilizce

Document ID (Org No.):

2001336641

pISSN:

1305-130X