Thermodynamic and Kinetic Parameters Concerning Complex Formation between 3-Hydroxy- and 1-Aminopyrene and Pyridine

Nursel ACAR; Özgül KOÇAK

Makale detayları

Thermodynamic and Kinetic Parameters Concerning Complex Formation between 3-Hydroxy- and 1-Aminopyrene and Pyridine

Yazarlar:

Nursel ACAR | Özgül KOÇAK

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Chemistry 2002 Vol.26 Issue 2, pp.201-211

Belge Tipi:

Makale

Yayın Tarihi:

1/2002

Belge Dili:

Türkçe

Document ID (Org No.):

2000729946

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527

Özet:

 

Systems formed by the pyrene derivatives 3-hydroxypyrene and 1-aminopyrene with   pyridine were studied. The thermodynamic and kinetic parameters of the   systems were calculated using the changes in the absorption and   emission spectra which occur due to hydrogen bond or complex formation. The   decrease of the formation rate constant in the series methylcyclohexane,   benzene, and o-chlorotoluene may be due to a more difficult formation of the   hydrogen bond complex due to the increase of the dielectric constant in the   solvent series.

 

Systems formed by the pyrene derivatives 3-hydroxypyrene and 1-aminopyrene with   pyridine were studied. The thermodynamic and kinetic parameters of the   systems were calculated using the changes in the absorption and   emission spectra which occur due to hydrogen bond or complex formation. The   decrease of the formation rate constant in the series methylcyclohexane,   benzene, and o-chlorotoluene may be due to a more difficult formation of the   hydrogen bond complex due to the increase of the dielectric constant in the   solvent series.

Makale detayları

Thermodynamic and Kinetic Parameters Concerning Complex Formation between 3-Hydroxy- and 1-Aminopyrene and Pyridine

Yazarlar: Nursel ACAR | Özgül KOÇAK

Yayıncı: TUBITAK

Dergi: Turkish Journal of Chemistry 2002 Vol.26 Issue 2, pp.201-211

Belge Tipi: Makale

Yayın Tarihi: 1/2002

Belge Dili: Türkçe

Document ID (Org No.): 2000729946

Sıklık: İki Aylık

eISSN: 1303-6130

pISSN: 1300-0527

Sayı

Yazarlar:

Nursel ACAR | Özgül KOÇAK

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Chemistry 2002 Vol.26 Issue 2, pp.201-211

Belge Tipi:

Makale

Yayın Tarihi:

1/2002

Belge Dili:

Türkçe

Document ID (Org No.):

2000729946

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527