The Influence of Solvents on Formation of the Molecular Geometry of [{Fe(salphen)}2O]

Mehmet KABAK; Ayhan ELMALI

Makale detayları

The Influence of Solvents on Formation of the Molecular Geometry of [{Fe(salphen)}2O]

Yazarlar:

Mehmet KABAK | Ayhan ELMALI

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Physics 1998 Vol.22 Issue 8, pp.797-802

Belge Tipi:

Makale

Yayın Tarihi:

7/1998

Belge Dili:

Türkçe

Document ID (Org No.):

2000763313

Sıklık:

İki Aylık

eISSN:

1303-6122

pISSN:

1300-0101

Anahtar kelimeler:

Özet:

 

The crystal structure and magnetic properties of the complex (I)=[\{Fe(salphen)\}2\-O]\cdot(C4\-H8SO) and (II)=[\{Fe(salphen)\}2O]\cdot(C4H8O2)\- (salphen H2=N,N'-o-phenylenebis\-(salicylidene-imine)) were recently reported [1, 2]. This complex crystallized with the solvents of dimethyl sulfoxide and dioxane. In this paper, we investigate the influence of the solvents on the formation of the molecular geometry and study the orbital mechanism of the magnetic super-exchange interactions of this complex.

 

The crystal structure and magnetic properties of the complex (I)=[\{Fe(salphen)\}2\-O]\cdot(C4\-H8SO) and (II)=[\{Fe(salphen)\}2O]\cdot(C4H8O2)\- (salphen H2=N,N'-o-phenylenebis\-(salicylidene-imine)) were recently reported [1, 2]. This complex crystallized with the solvents of dimethyl sulfoxide and dioxane. In this paper, we investigate the influence of the solvents on the formation of the molecular geometry and study the orbital mechanism of the magnetic super-exchange interactions of this complex.

Makale detayları

The Influence of Solvents on Formation of the Molecular Geometry of [{Fe(salphen)}2O]

Yazarlar:

Mehmet KABAK | Ayhan ELMALI

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Physics 1998 Vol.22 Issue 8, pp.797-802

Belge Tipi:

Makale

Yayın Tarihi:

7/1998

Belge Dili:

Türkçe

Document ID (Org No.):

2000763313

Sıklık:

İki Aylık

eISSN:

1303-6122

pISSN:

1300-0101

Turk. J. Phys.

22

(1998)

797-802. Full text: pdf Other articles published in the same issue: Turk. J. Phys.

vol.22

iss.8.

Sayı

Makale detayları

The Influence of Solvents on Formation of the Molecular Geometry of [{Fe(salphen)}2O]

Yazarlar: Mehmet KABAK | Ayhan ELMALI

Yayıncı: TUBITAK

Dergi: Turkish Journal of Physics 1998 Vol.22 Issue 8, pp.797-802

Belge Tipi: Makale

Yayın Tarihi: 7/1998

Belge Dili: Türkçe

Document ID (Org No.): 2000763313

Sıklık: İki Aylık

eISSN: 1303-6122

pISSN: 1300-0101

Turk. J. Phys.

22

(1998)

797-802. Full text: pdf Other articles published in the same issue: Turk. J. Phys.

vol.22

iss.8.

Sayı

Yazarlar:

Mehmet KABAK | Ayhan ELMALI

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Physics 1998 Vol.22 Issue 8, pp.797-802

Belge Tipi:

Makale

Yayın Tarihi:

7/1998

Belge Dili:

Türkçe

Document ID (Org No.):

2000763313

Sıklık:

İki Aylık

eISSN:

1303-6122

pISSN:

1300-0101