Synthesis, Spectroscopic Analysis, and Anti-Bacterial Studies of Pd(II) Complexes of Phosphine and Hydrazone Derivatives

Ahmed Shaker Marmus

Makale detayları

Synthesis, Spectroscopic Analysis, and Anti-Bacterial Studies of Pd(II) Complexes of Phosphine and Hydrazone Derivatives

Yazarlar:

Ahmed Shaker Marmus

Yayıncı:

Turkish Chemical Society

Ana Başlıklar:

Transition Metal Chemistry

Dergi:

Journal of the Turkish Chemical Society Section A: Chemistry Vol.11 Issue 1, pp.245-252

Belge Tipi:

Makale

Yayın Tarihi:

4/2024

Belge Dili:

İngilizce

Document ID (Org No.):

2001303738

pISSN:

2149-0120

Anahtar kelimeler:

Özet:

 This study reports the synthesis of seven hydrazone derivative complexes by the treatment equivalent molar of the phosphine ligand Ph2PCH2nPPh2 where n 1 dppm; n2 dppe; n3 dppp; n4 dppb; CH2n  Cp2Fe with Pddbeoz2 afforded complexes of the type Pddbeoz2diphos and Pddbeoz2dppm2, whereas the reaction of two moles of Ph3P with Pddbeoz2 gave a complex Pddbeoz2PPh32 in good yield. CHN analysis, conductivity measurements, Fourier Transform Infrared FT-IR, 1H, and 31P-NMR, were used to investigate the structural geometries of the complexes. Further, the biological activity of the synthesized complexes was evaluated against three pathogenic bacteria Pseudomonas aeruginosa, Bacillus subtilis, and Escherichia coli using the well diffusion method, the synthesized complexes displayed moderate to good inhibitory activity, and the Pddbeoz2dppf complex exhibited the highest inhibitory activity with DIZ is 24, 27, and 28 mm against the three pathogenic bacteria, respectively.

 This study reports the synthesis of seven hydrazone derivative complexes by the treatment equivalent molar of the phosphine ligand Ph2PCH2nPPh2 where n 1 dppm; n2 dppe; n3 dppp; n4 dppb; CH2n  Cp2Fe with Pddbeoz2 afforded complexes of the type Pddbeoz2diphos and Pddbeoz2dppm2, whereas the reaction of two moles of Ph3P with Pddbeoz2 gave a complex Pddbeoz2PPh32 in good yield. CHN analysis, conductivity measurements, Fourier Transform Infrared FT-IR, 1H, and 31P-NMR, were used to investigate the structural geometries of the complexes. Further, the biological activity of the synthesized complexes was evaluated against three pathogenic bacteria Pseudomonas aeruginosa, Bacillus subtilis, and Escherichia coli using the well diffusion method, the synthesized complexes displayed moderate to good inhibitory activity, and the Pddbeoz2dppf complex exhibited the highest inhibitory activity with DIZ is 24, 27, and 28 mm against the three pathogenic bacteria, respectively.

 This study reports the synthesis of seven hydrazone derivative complexes by the treatment equivalent molar of the phosphine ligand Ph2PCH2nPPh2 where n 1 dppm; n2 dppe; n3 dppp; n4 dppb; CH2n  Cp2Fe with Pddbeoz2 afforded complexes of the type Pddbeoz2diphos and Pddbeoz2dppm2, whereas the reaction of two moles of Ph3P with Pddbeoz2 gave a complex Pddbeoz2PPh32 in good yield. CHN analysis, conductivity measurements, Fourier Transform Infrared FT-IR, 1H, and 31P-NMR, were used to investigate the structural geometries of the complexes. Further, the biological activity of the synthesized complexes was evaluated against three pathogenic bacteria Pseudomonas aeruginosa, Bacillus subtilis, and Escherichia coli using the well diffusion method, the synthesized complexes displayed moderate to good inhibitory activity, and the Pddbeoz2dppf complex exhibited the highest inhibitory activity with DIZ is 24, 27, and 28 mm against the three pathogenic bacteria, respectively.

 This study reports the synthesis of seven hydrazone derivative complexes by the treatment equivalent molar of the phosphine ligand Ph2PCH2nPPh2 where n 1 dppm; n2 dppe; n3 dppp; n4 dppb; CH2n  Cp2Fe with Pddbeoz2 afforded complexes of the type Pddbeoz2diphos and Pddbeoz2dppm2, whereas the reaction of two moles of Ph3P with Pddbeoz2 gave a complex Pddbeoz2PPh32 in good yield. CHN analysis, conductivity measurements, Fourier Transform Infrared FT-IR, 1H, and 31P-NMR, were used to investigate the structural geometries of the complexes. Further, the biological activity of the synthesized complexes was evaluated against three pathogenic bacteria Pseudomonas aeruginosa, Bacillus subtilis, and Escherichia coli using the well diffusion method, the synthesized complexes displayed moderate to good inhibitory activity, and the Pddbeoz2dppf complex exhibited the highest inhibitory activity with DIZ is 24, 27, and 28 mm against the three pathogenic bacteria, respectively.

Makale detayları

Synthesis, Spectroscopic Analysis, and Anti-Bacterial Studies of Pd(II) Complexes of Phosphine and Hydrazone Derivatives

Yazarlar:

Ahmed Shaker Marmus

Yayıncı:

Turkish Chemical Society

Ana Başlıklar:

Transition Metal Chemistry

Dergi:

Journal of the Turkish Chemical Society Section A: Chemistry Vol.11 Issue 1, pp.245-252

Belge Tipi:

Makale

Yayın Tarihi:

4/2024

Belge Dili:

İngilizce

Document ID (Org No.):

2001303738

pISSN:

2149-0120

hydrazone

phosphine

Palladium

metal complexes

anti-bacterial activity

Sayı

Makale detayları

Synthesis, Spectroscopic Analysis, and Anti-Bacterial Studies of Pd(II) Complexes of Phosphine and Hydrazone Derivatives

Yazarlar: Ahmed Shaker Marmus

Yayıncı: Turkish Chemical Society

Ana Başlıklar: Transition Metal Chemistry

Dergi: Journal of the Turkish Chemical Society Section A: Chemistry Vol.11 Issue 1, pp.245-252

Belge Tipi: Makale

Yayın Tarihi: 4/2024

Belge Dili: İngilizce

Document ID (Org No.): 2001303738

pISSN: 2149-0120

hydrazone

phosphine

Palladium

metal complexes

anti-bacterial activity

Sayı

Yazarlar:

Ahmed Shaker Marmus

Yayıncı:

Turkish Chemical Society

Ana Başlıklar:

Transition Metal Chemistry

Dergi:

Journal of the Turkish Chemical Society Section A: Chemistry Vol.11 Issue 1, pp.245-252

Belge Tipi:

Makale

Yayın Tarihi:

4/2024

Belge Dili:

İngilizce

Document ID (Org No.):

2001303738

pISSN:

2149-0120