The Synthesis of New Aryl Boron-Dipyrromethene Compounds: Photophysical and pH Responsive Properties

Gökhan Sevinç; Mustafa Hayvalı

doi:https://doi.org/10.18596/jotcsa.372452

Makale detayları

The Synthesis of New Aryl Boron-Dipyrromethene Compounds: Photophysical and pH Responsive Properties

Yazarlar:

Gökhan Sevinç | Mustafa Hayvalı

Yayıncı:

Turkish Chemical Society

Ana Başlıklar:

Kimya mühendisliği

Dergi:

Journal of the Turkish Chemical Society Section A: Chemistry 2018 Vol.5 Issue 2, pp.433-444

Belge Tipi:

Makale

Yayın Tarihi:

12/2017

Belge Dili:

İngilizce

Document ID (Org No.):

2000503132

Sıklık:

Üç Aylık

eISSN:

2149-0120

DOI:

https://doi.org/10.18596/jotcsa.372452

Özet:

 

In
this work, a convenient protocol enabled the synthesis of novel Arylated
Borondipyrromethene (BODIPY) compounds was applied that synthesis yields found
to be higher than classical alkyl substituted analogue. Arylated chromophores
exhibited the broader red-shifted absorption and fluorescence bands with higher
stokes shifts with regard to reference Borondipyrromethene compound
(4,4’-difluoro-8-phenyl-1,3,5,7-tetramethyl-4-bora-3a,4a-diaza-s-indacene,). We
interested in the electron transfer mechanism of compound BDPNH2
which have amine subunit to alkyl substituted reference. The fluorescence
enhancement of this compound in acidic media was associated with the
inactivation of the acceptor type photoinduced electron transfer mechanism by
fluorimetric measurements. Our results are helpful for designing new
photosensitizers and for applications in the study of the molecular
photochemistry.

Makale detayları

The Synthesis of New Aryl Boron-Dipyrromethene Compounds: Photophysical and pH Responsive Properties

Yazarlar: Gökhan Sevinç | Mustafa Hayvalı

Yayıncı: Turkish Chemical Society

Ana Başlıklar: Kimya mühendisliği

Dergi: Journal of the Turkish Chemical Society Section A: Chemistry 2018 Vol.5 Issue 2, pp.433-444

Belge Tipi: Makale

Yayın Tarihi: 12/2017

Belge Dili: İngilizce

Document ID (Org No.): 2000503132

Sıklık: Üç Aylık

eISSN: 2149-0120

DOI: https://doi.org/10.18596/jotcsa.372452

Sayı

Yazarlar:

Gökhan Sevinç | Mustafa Hayvalı

Yayıncı:

Turkish Chemical Society

Ana Başlıklar:

Kimya mühendisliği

Dergi:

Journal of the Turkish Chemical Society Section A: Chemistry 2018 Vol.5 Issue 2, pp.433-444

Belge Tipi:

Makale

Yayın Tarihi:

12/2017

Belge Dili:

İngilizce

Document ID (Org No.):

2000503132

Sıklık:

Üç Aylık

eISSN:

2149-0120

DOI:

https://doi.org/10.18596/jotcsa.372452