Synthesis and characterization of a novel 3-amino-1,2,4-triazole lead(II) coordination polymer

Şebnem Esen SÖZERLİ; Arzu ÖZEN; İbrahim KANİ; Deniz DEMİR

doi:https://doi.org/10.3906/kim-1308-19

Makale detayları

Synthesis and characterization of a novel 3-amino-1,2,4-triazole lead(II) coordination polymer

Yazarlar:

Şebnem Esen SÖZERLİ | Arzu ÖZEN | İbrahim KANİ | Deniz DEMİR

Yayıncı:

TUBITAK

Ana Başlıklar:

Kimya ve ilgili bilimler

Dergi:

Turkish Journal of Chemistry 2014 Vol.38 Issue 4, pp.671-678

Belge Tipi:

Makale

Yayın Tarihi:

3/2014

Belge Dili:

İngilizce

Document ID (Org No.):

2000727145

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527

DOI:

https://doi.org/10.3906/kim-1308-19

Özet:

 

A novel [Pb2(m-atrz)2(m-CH3COO)(CH3COO)]n (atrz = 3-amino-1,2,4-triazole) complex was synthesized and characterized by IR spectroscopy, thermogravimetric analysis, and single crystal X-ray diffraction. The molecular structure shows that the complex is a coordination polymer in which there are 2 different lead(II) ions with coordination number of 5, Pb(2), and, with a coordination number of 4, Pb(1). Each atrz acts as a bridging ligand between 2 Pb(II) ions through the 2 adjacent nitrogen atoms of the triazole ring. The acetate anions show different types of coordination mode: one acts as a bridge by coordination of the same oxygen atom with Pb(II) ions and the other as a monodentate coordination by one of the oxygen atoms with Pb(2).

 

A novel [Pb2(m-atrz)2(m-CH3COO)(CH3COO)]n (atrz = 3-amino-1,2,4-triazole) complex was synthesized and characterized by IR spectroscopy, thermogravimetric analysis, and single crystal X-ray diffraction. The molecular structure shows that the complex is a coordination polymer in which there are 2 different lead(II) ions with coordination number of 5, Pb(2), and, with a coordination number of 4, Pb(1). Each atrz acts as a bridging ligand between 2 Pb(II) ions through the 2 adjacent nitrogen atoms of the triazole ring. The acetate anions show different types of coordination mode: one acts as a bridge by coordination of the same oxygen atom with Pb(II) ions and the other as a monodentate coordination by one of the oxygen atoms with Pb(2).

Makale detayları

Synthesis and characterization of a novel 3-amino-1,2,4-triazole lead(II) coordination polymer

Yazarlar: Şebnem Esen SÖZERLİ | Arzu ÖZEN | İbrahim KANİ | Deniz DEMİR

Yayıncı: TUBITAK

Ana Başlıklar: Kimya ve ilgili bilimler

Dergi: Turkish Journal of Chemistry 2014 Vol.38 Issue 4, pp.671-678

Belge Tipi: Makale

Yayın Tarihi: 3/2014

Belge Dili: İngilizce

Document ID (Org No.): 2000727145

Sıklık: İki Aylık

eISSN: 1303-6130

pISSN: 1300-0527

DOI: https://doi.org/10.3906/kim-1308-19

Sayı

Yazarlar:

Şebnem Esen SÖZERLİ | Arzu ÖZEN | İbrahim KANİ | Deniz DEMİR

Yayıncı:

TUBITAK

Ana Başlıklar:

Kimya ve ilgili bilimler

Dergi:

Turkish Journal of Chemistry 2014 Vol.38 Issue 4, pp.671-678

Belge Tipi:

Makale

Yayın Tarihi:

3/2014

Belge Dili:

İngilizce

Document ID (Org No.):

2000727145

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527

DOI:

https://doi.org/10.3906/kim-1308-19