Determination of Heavy Metal Concentrations In Natural Clay Mineral Samples From Quarries In Turkey

Aybaba Hançerlioğulları; Şeref Turhan; Arif Baştuğ; Yosef G. Ali Madee

Makale detayları

Determination of Heavy Metal Concentrations In Natural Clay Mineral Samples From Quarries In Turkey

Yazarlar:

Aybaba Hançerlioğulları | Şeref Turhan | Arif Baştuğ | Yosef G. Ali Madee

Yayıncı:

Gazi University

Ana Başlıklar:

Nükleer Uygulamalar | Mineraloji-Petrografi | İklim Değişikliği Süreçleri

Dergi:

Politeknik Dergisi Vol.26 Issue 4, pp.1691-1696

Belge Tipi:

Makale

Yayın Tarihi:

1/2023

Belge Dili:

İngilizce

Document ID (Org No.):

2001306322

pISSN:

2147-9429

Anahtar kelimeler:

Özet:

 Environmental pollution of heavy metals is increasingly becoming a problem and has become of great concern due to the adverse effects it is causing around the world. Today, various chemical, biological, and physical pollutants arising as a result of rapidpopulation growth, industrialization, and excessive mining activities have become a major problem that adversely affects people, animals, plants, organisms, and ecosystems all over the world. Sepiolite is a clay mineral containing hydrated magnesium silicate and widely used in construction, agriculture, food, fertilizer, pharmaceutical, detergent, cosmetics, paint, paper, etc. The average concentrations of Al, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Rb, Sr, Zr, Cd, Sn, Ba and Pb analyzed in sepiolite samples collected from three quarries Polatlı, Beylikova, and Sivrihisar located in the Central Anatolian Region of Turkey using EDXRF spectroscopy were found as 5456.5, 361.0, 42.0, 15.5, 65.2, 3831.5, 8.6, 23.7, 7.8, 11.8, 5.3, 13.7, 1183.2, 25.3, 3.7, 7.2, 131.9 and 5.3 mgkg, respectively. The average enrichment factor values of V, Cr, Co, Ni, Cu, Zn, As, Sr, Cd, Sn, Ba, and Pb indicated minimal to extremely high enrichment in sepiolite. The values of non-carcinogenic risk index and cancer risk estimated to evaluate potentially health risks caused by PTEs in sepiolite samples were within the acceptable limit and the safe range except for the Beylikova quarry.

 Environmental pollution of heavy metals is increasingly becoming a problem and has become of great concern due to the adverse effects it is causing around the world. Today, various chemical, biological, and physical pollutants arising as a result of rapidpopulation growth, industrialization, and excessive mining activities have become a major problem that adversely affects people, animals, plants, organisms, and ecosystems all over the world. Sepiolite is a clay mineral containing hydrated magnesium silicate and widely used in construction, agriculture, food, fertilizer, pharmaceutical, detergent, cosmetics, paint, paper, etc. The average concentrations of Al, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Rb, Sr, Zr, Cd, Sn, Ba and Pb analyzed in sepiolite samples collected from three quarries Polatlı, Beylikova, and Sivrihisar located in the Central Anatolian Region of Turkey using EDXRF spectroscopy were found as 5456.5, 361.0, 42.0, 15.5, 65.2, 3831.5, 8.6, 23.7, 7.8, 11.8, 5.3, 13.7, 1183.2, 25.3, 3.7, 7.2, 131.9 and 5.3 mgkg, respectively. The average enrichment factor values of V, Cr, Co, Ni, Cu, Zn, As, Sr, Cd, Sn, Ba, and Pb indicated minimal to extremely high enrichment in sepiolite. The values of non-carcinogenic risk index and cancer risk estimated to evaluate potentially health risks caused by PTEs in sepiolite samples were within the acceptable limit and the safe range except for the Beylikova quarry.

 Environmental pollution of heavy metals is increasingly becoming a problem and has become of great concern due to the adverse effects it is causing around the world. Today, various chemical, biological, and physical pollutants arising as a result of rapidpopulation growth, industrialization, and excessive mining activities have become a major problem that adversely affects people, animals, plants, organisms, and ecosystems all over the world. Sepiolite is a clay mineral containing hydrated magnesium silicate and widely used in construction, agriculture, food, fertilizer, pharmaceutical, detergent, cosmetics, paint, paper, etc. The average concentrations of Al, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Rb, Sr, Zr, Cd, Sn, Ba and Pb analyzed in sepiolite samples collected from three quarries Polatlı, Beylikova, and Sivrihisar located in the Central Anatolian Region of Turkey using EDXRF spectroscopy were found as 5456.5, 361.0, 42.0, 15.5, 65.2, 3831.5, 8.6, 23.7, 7.8, 11.8, 5.3, 13.7, 1183.2, 25.3, 3.7, 7.2, 131.9 and 5.3 mgkg, respectively. The average enrichment factor values of V, Cr, Co, Ni, Cu, Zn, As, Sr, Cd, Sn, Ba, and Pb indicated minimal to extremely high enrichment in sepiolite. The values of non-carcinogenic risk index and cancer risk estimated to evaluate potentially health risks caused by PTEs in sepiolite samples were within the acceptable limit and the safe range except for the Beylikova quarry.

 Ciddi çevre sorunları haline gelen ağır metaller HMler, genellikle maden kaynaklarının geliştirilmesi de dahil olmak üzere insan faaliyetlerinden kaynaklanmaktadır. Sepiyolit, hidratlanmış magnezyum silikat içeren bir kil mineralidir ve inşaat, tarım, gıda, gübre, ilaç, deterjan, kozmetik, boya, kağıt vb. alanlarda yaygın olarak kullanılmaktadır. Bu çalışmada, üç ocaktan toplanan sepiolit numunelerindeki bazı HMlerin konsantrasyonları incelenmiştir. Türkiyenin İç Anadolu Bölgesinde bulunan Polatlı, Beylikova ve Sivrihisar enerji dağılımlı X-ışını floresans spektroskopisi kullanılarak belirlenmiş ve ayrıca HMler için zenginleştirme faktörü EF hesaplanmıştır. Sepiyolit numunelerinde analiz edilen Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Zr, Cd, Sn ve Pb ortalama konsantrasyonları 361, 42, 16, 65, 3832, 9, Sırasıyla 24, 8, 12, 5, 25, 4, 7 ve 5 mgkg. V, Co, Ni, Pb, As, Cd ve Snnin ortalama EF değerleri, sepiolit numunelerinde önemli ila aşırı yüksek zenginleşmeyi göstermektedir.

Makale detayları

Determination of Heavy Metal Concentrations In Natural Clay Mineral Samples From Quarries In Turkey

Yazarlar:

Aybaba Hançerlioğulları | Şeref Turhan | Arif Baştuğ | Yosef G. Ali Madee

Yayıncı:

Gazi University

Ana Başlıklar:

Nükleer Uygulamalar | Mineraloji-Petrografi | İklim Değişikliği Süreçleri

Dergi:

Politeknik Dergisi Vol.26 Issue 4, pp.1691-1696

Belge Tipi:

Makale

Yayın Tarihi:

1/2023

Belge Dili:

İngilizce

Document ID (Org No.):

2001306322

pISSN:

2147-9429

Sepiolite

Heavy metals

Enrichment Factor

EDXRF

TürkiyeSepiyolit

Ağır metaller

Zenginleştirme Faktörü

EDXRF

Türkiye

Sayı

Makale detayları

Yazarlar: Aybaba Hançerlioğulları | Şeref Turhan | Arif Baştuğ | Yosef G. Ali Madee

Yayıncı: Gazi University

Ana Başlıklar: Nükleer Uygulamalar | Mineraloji-Petrografi | İklim Değişikliği Süreçleri

Dergi: Politeknik Dergisi Vol.26 Issue 4, pp.1691-1696

Belge Tipi: Makale

Yayın Tarihi: 1/2023

Belge Dili: İngilizce

Document ID (Org No.): 2001306322

pISSN: 2147-9429

Sayı

Yazarlar:

Aybaba Hançerlioğulları | Şeref Turhan | Arif Baştuğ | Yosef G. Ali Madee

Yayıncı:

Gazi University

Ana Başlıklar:

Nükleer Uygulamalar | Mineraloji-Petrografi | İklim Değişikliği Süreçleri

Dergi:

Politeknik Dergisi Vol.26 Issue 4, pp.1691-1696

Belge Tipi:

Makale

Yayın Tarihi:

1/2023

Belge Dili:

İngilizce

Document ID (Org No.):

2001306322

pISSN:

2147-9429