Tribological behavior and quantum chemical calculations of protic ionic liquids: synthesis, spectroscopic, and thermal properties

Ahmet KARADAĞ; Hüseyin AKBAŞ; Duran KARAKAŞ; Kadir Cihan TEKİN; Erdem KORKMAZER

Makale detayları

Tribological behavior and quantum chemical calculations of protic ionic liquids: synthesis, spectroscopic, and thermal properties

Yazarlar:

Ahmet KARADAĞ | Hüseyin AKBAŞ | Duran KARAKAŞ | Kadir Cihan TEKİN | Erdem KORKMAZER

Yayıncı:

TUBITAK

Ana Başlıklar:

Uygulamalı fizik

Dergi:

Turkish Journal of Chemistry 2019 Vol.43 Issue 3, pp.766-777

Belge Tipi:

Makale

Yayın Tarihi:

6/2019

Belge Dili:

İngilizce

Document ID (Org No.):

2000725659

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527

Özet:

 


Protic ionic liquids (PILs) were synthesized through a stoichiometric neutralization reaction between 2,2′ - (ethylenedioxy)-bis(ethylamine) { Edbea} and various acids (formic, acetic, boric, decanoic, and gentisic acid). The PILs were characterized by elemental analyses, FTIR, 1 H and 13 C NMR spectroscopy, and thermogravimetric analysis. All the PILs except PIL3 were liquid at room temperature. The viscosity of the PILs (PIL1, 2, 4, 5) was measured using a cone-and-plate viscometer at ambient temperature. Quantum chemical calculations were used to explain the cation/anion ratio in the PILs. Reaction energies in the gas phase calculated at M062X/6-311+G(d,p) level were used to determine the cation/anion ratio. A sliding wear test was conducted at room temperature using an AA7075 disc specimen against a stationary 100Cr6 steel ball. The wear protection of PILs and 15W40 engine oil was determined by considering the volume loss of AA7075.

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Makale detayları

Tribological behavior and quantum chemical calculations of protic ionic liquids: synthesis, spectroscopic, and thermal properties

Yazarlar: Ahmet KARADAĞ | Hüseyin AKBAŞ | Duran KARAKAŞ | Kadir Cihan TEKİN | Erdem KORKMAZER

Yayıncı: TUBITAK

Ana Başlıklar: Uygulamalı fizik

Dergi: Turkish Journal of Chemistry 2019 Vol.43 Issue 3, pp.766-777

Belge Tipi: Makale

Yayın Tarihi: 6/2019

Belge Dili: İngilizce

Document ID (Org No.): 2000725659

Sıklık: İki Aylık

eISSN: 1303-6130

pISSN: 1300-0527

Sayı

Yazarlar:

Ahmet KARADAĞ | Hüseyin AKBAŞ | Duran KARAKAŞ | Kadir Cihan TEKİN | Erdem KORKMAZER

Yayıncı:

TUBITAK

Ana Başlıklar:

Uygulamalı fizik

Dergi:

Turkish Journal of Chemistry 2019 Vol.43 Issue 3, pp.766-777

Belge Tipi:

Makale

Yayın Tarihi:

6/2019

Belge Dili:

İngilizce

Document ID (Org No.):

2000725659

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527