Synthesis and Characterization of New Tridentate Iminooxime Ligands and Their Co(III) Complexes

Hasene MUTLU and Gazi İREZ; Gazi İREZ

Makale detayları

Synthesis and Characterization of New Tridentate Iminooxime Ligands and Their Co(III) Complexes

Yazarlar:

Hasene MUTLU and Gazi İREZ | Gazi İREZ

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Chemistry 2008 Vol.32 Issue 6, pp.731-741

Belge Tipi:

Makale

Yayın Tarihi:

5/2008

Belge Dili:

Türkçe

Document ID (Org No.):

2000728409

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527

Özet:

 

In this study, (hydroxyimino)(2-phenyl(1,2,3,4-tetrahydroquinazolin-  2-yl))methane (H2L1) and (hydroxyimino)(2-(2-thienyl)(1,2,3,4-  tetrahydroquinazolin-2-yl))methane (H2L2) were synthesized by the  condensation of 2-(hydroxyimino)-1-phenylethan-1-one (INAP) and  2-(hydroxyimino)-1-(2-thienyl)ethan-1-one (INAT) with  2-aminobenzylamine (2-ABA).  Complexes of these ligands with Co3+  were prepared with a metal:ligand ratio of 1:2.  The ligands and their  complexes were elucidated on the basis of elemental analyses, AAS,  FT-IR, 1H- and 13C-NMR spectra, mass spectra, magnetic  susceptibility measurements, and molar conductivity.

 

In this study, (hydroxyimino)(2-phenyl(1,2,3,4-tetrahydroquinazolin-  2-yl))methane (H2L1) and (hydroxyimino)(2-(2-thienyl)(1,2,3,4-  tetrahydroquinazolin-2-yl))methane (H2L2) were synthesized by the  condensation of 2-(hydroxyimino)-1-phenylethan-1-one (INAP) and  2-(hydroxyimino)-1-(2-thienyl)ethan-1-one (INAT) with  2-aminobenzylamine (2-ABA).  Complexes of these ligands with Co3+  were prepared with a metal:ligand ratio of 1:2.  The ligands and their  complexes were elucidated on the basis of elemental analyses, AAS,  FT-IR, 1H- and 13C-NMR spectra, mass spectra, magnetic  susceptibility measurements, and molar conductivity.

Makale detayları

Synthesis and Characterization of New Tridentate Iminooxime Ligands and Their Co(III) Complexes

Yazarlar: Hasene MUTLU and Gazi İREZ | Gazi İREZ

Yayıncı: TUBITAK

Dergi: Turkish Journal of Chemistry 2008 Vol.32 Issue 6, pp.731-741

Belge Tipi: Makale

Yayın Tarihi: 5/2008

Belge Dili: Türkçe

Document ID (Org No.): 2000728409

Sıklık: İki Aylık

eISSN: 1303-6130

pISSN: 1300-0527

Sayı

Yazarlar:

Hasene MUTLU and Gazi İREZ | Gazi İREZ

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Chemistry 2008 Vol.32 Issue 6, pp.731-741

Belge Tipi:

Makale

Yayın Tarihi:

5/2008

Belge Dili:

Türkçe

Document ID (Org No.):

2000728409

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527