The synthesis, characterization, and catalytic properties of (κ 2 − C, N)-palladacycles with N-heterocyclic carbene-based ancillary ligands

MUHAMMET EMİN GÜNAY; GÜLCAN GENÇAY ÇOĞAŞLIOĞLU; RUKİYE FIRINCI

Makale detayları

The synthesis, characterization, and catalytic properties of (κ 2 − C, N)-palladacycles with N-heterocyclic carbene-based ancillary ligands

Yazarlar:

MUHAMMET EMİN GÜNAY | GÜLCAN GENÇAY ÇOĞAŞLIOĞLU | RUKİYE FIRINCI

Yayıncı:

TUBITAK

Ana Başlıklar:

Uygulamalı fizik

Dergi:

Turkish Journal of Chemistry 2015 Vol.39 Issue 6, pp.1310-1316

Belge Tipi:

Makale

Yayın Tarihi:

12/2015

Belge Dili:

İngilizce

Document ID (Org No.):

2000726752

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527

Özet:

 

Novel five-membered (κ2−C,N)κ2−C,N)\kappa ^{2}-C,N)-palladacyclic complexes were prepared from the reaction of the corresponding acetate-bridged palladacycle dimer with N-heterocyclic carbene (NHC) ligands in high yields. Palladacyclic complexes (\textbf{3}) were fully characterized by elemental analysis and 11^{1}H and 1313^{13}C NMR spectroscopy. Palladacyclic complexes were tested as catalyst for the C--C bond forming reaction. These complexes were found to be efficient catalysts for the Suzuki--Miyaura reaction of aryl bromides.

 

Novel five-membered (κ2−C,N)κ2−C,N)\kappa ^{2}-C,N)-palladacyclic complexes were prepared from the reaction of the corresponding acetate-bridged palladacycle dimer with N-heterocyclic carbene (NHC) ligands in high yields. Palladacyclic complexes (\textbf{3}) were fully characterized by elemental analysis and 11^{1}H and 1313^{13}C NMR spectroscopy. Palladacyclic complexes were tested as catalyst for the C--C bond forming reaction. These complexes were found to be efficient catalysts for the Suzuki--Miyaura reaction of aryl bromides.

Makale detayları

The synthesis, characterization, and catalytic properties of (κ 2 − C, N)-palladacycles with N-heterocyclic carbene-based ancillary ligands

Yazarlar: MUHAMMET EMİN GÜNAY | GÜLCAN GENÇAY ÇOĞAŞLIOĞLU | RUKİYE FIRINCI

Yayıncı: TUBITAK

Ana Başlıklar: Uygulamalı fizik

Dergi: Turkish Journal of Chemistry 2015 Vol.39 Issue 6, pp.1310-1316

Belge Tipi: Makale

Yayın Tarihi: 12/2015

Belge Dili: İngilizce

Document ID (Org No.): 2000726752

Sıklık: İki Aylık

eISSN: 1303-6130

pISSN: 1300-0527

Sayı

Yazarlar:

MUHAMMET EMİN GÜNAY | GÜLCAN GENÇAY ÇOĞAŞLIOĞLU | RUKİYE FIRINCI

Yayıncı:

TUBITAK

Ana Başlıklar:

Uygulamalı fizik

Dergi:

Turkish Journal of Chemistry 2015 Vol.39 Issue 6, pp.1310-1316

Belge Tipi:

Makale

Yayın Tarihi:

12/2015

Belge Dili:

İngilizce

Document ID (Org No.):

2000726752

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527