Palladium-catalyzed ligand-free and efficient Suzuki--Miyaura reaction of NNN-methyliminodiacetic acid boronates in water

Chun LIU; Xinmin LI; Xinnan WANG; Jieshan QIU

Makale detayları

Palladium-catalyzed ligand-free and efficient Suzuki--Miyaura reaction of NNN-methyliminodiacetic acid boronates in water

Yazarlar:

Chun LIU | Xinmin LI | Xinnan WANG | Jieshan QIU

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Chemistry 2015 Vol.39 Issue 6, pp.1208-1215

Belge Tipi:

Makale

Yayın Tarihi:

12/2015

Belge Dili:

Türkçe

Document ID (Org No.):

2000726726

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527

Özet:

 

A green and efficient protocol has been developed for the Pd(OAc)22_{2}-catalyzed ligand-free Suzuki--Miyaura reaction of NNN-methyliminodiacetic acid (MIDA) boronates in water. In the presence of Pd(OAc)22_{2} as a catalyst and (iii-Pr)22_{2}NH as a base, the cross-coupling reactions of aryl bromides with aryl MIDA boronates proceeded smoothly in water without any surfactant, and various functional groups were tolerated under the optimized conditions.

 

A green and efficient protocol has been developed for the Pd(OAc)22_{2}-catalyzed ligand-free Suzuki--Miyaura reaction of NNN-methyliminodiacetic acid (MIDA) boronates in water. In the presence of Pd(OAc)22_{2} as a catalyst and (iii-Pr)22_{2}NH as a base, the cross-coupling reactions of aryl bromides with aryl MIDA boronates proceeded smoothly in water without any surfactant, and various functional groups were tolerated under the optimized conditions.

Makale detayları

Palladium-catalyzed ligand-free and efficient Suzuki--Miyaura reaction of NNN-methyliminodiacetic acid boronates in water

Yazarlar: Chun LIU | Xinmin LI | Xinnan WANG | Jieshan QIU

Yayıncı: TUBITAK

Dergi: Turkish Journal of Chemistry 2015 Vol.39 Issue 6, pp.1208-1215

Belge Tipi: Makale

Yayın Tarihi: 12/2015

Belge Dili: Türkçe

Document ID (Org No.): 2000726726

Sıklık: İki Aylık

eISSN: 1303-6130

pISSN: 1300-0527

Sayı

Yazarlar:

Chun LIU | Xinmin LI | Xinnan WANG | Jieshan QIU

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Chemistry 2015 Vol.39 Issue 6, pp.1208-1215

Belge Tipi:

Makale

Yayın Tarihi:

12/2015

Belge Dili:

Türkçe

Document ID (Org No.):

2000726726

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527