A novel n-pivot macrocyclic ligand and its Cobalt(II) phthalocyanine derivative: synthesis, characterization and extractant properties

Halil Zeki GÖK; Yaşar GÖK

Makale detayları

A novel n-pivot macrocyclic ligand and its Cobalt(II) phthalocyanine derivative: synthesis, characterization and extractant properties

Yazarlar:

Halil Zeki GÖK | Yaşar GÖK

Yayıncı:

Burdur Mehmet Akif Ersoy University

Ana Başlıklar:

Uygulamalı fizik

Dergi:

Scientific Journal of Mehmet Akif Ersoy University 2018 Vol.1 Issue 2, pp.40-45

Belge Tipi:

Makale

Yayın Tarihi:

11/2018

Belge Dili:

İngilizce

Document ID (Org No.):

2000571600

Sıklık:

İki Yıllık

eISSN:

2651-3722

Özet:

 


In this
study, the synthesis of a novel N-pivot 12-membered macrocyclic ligand with
mixed donor atoms 2, which is a
phthalonitrile derivative, and a new cobalt(II) phthalocyanine complex 3 obtained by cyclotetramerization
reaction of  2 were described.  Newly synthesized
compounds were characterized by using several spectroscopic techniques such as
IR, UV-Vis, 1H and 13C NMR, MS and elemental analysis.
These macrocyclic systems 2 and 3 were investigated as extractants in
liquid-liquid extraction technique to reveal metal ion binding capability
towards transition metals such as Ag(I), Hg(II), Cd(II), Zn(II), Cu(II),
Ni(II), Pb(II) and Co(II). The highest
extractability from aqueous phase to organic phase was found for Hg(II) cation
over the other metal cations with cobalt(II) phthalocyanine 3. The extraction percentage of Hg(II)
cation from aqueous phase to chloroform in the presence of cobalt(II)
phthalocyanine 3 as extractant was
found as 96.0%. 


.

Makale detayları

A novel n-pivot macrocyclic ligand and its Cobalt(II) phthalocyanine derivative: synthesis, characterization and extractant properties

Yazarlar: Halil Zeki GÖK | Yaşar GÖK

Yayıncı: Burdur Mehmet Akif Ersoy University

Ana Başlıklar: Uygulamalı fizik

Dergi: Scientific Journal of Mehmet Akif Ersoy University 2018 Vol.1 Issue 2, pp.40-45

Belge Tipi: Makale

Yayın Tarihi: 11/2018

Belge Dili: İngilizce

Document ID (Org No.): 2000571600

Sıklık: İki Yıllık

eISSN: 2651-3722

Sayı

Yazarlar:

Halil Zeki GÖK | Yaşar GÖK

Yayıncı:

Burdur Mehmet Akif Ersoy University

Ana Başlıklar:

Uygulamalı fizik

Dergi:

Scientific Journal of Mehmet Akif Ersoy University 2018 Vol.1 Issue 2, pp.40-45

Belge Tipi:

Makale

Yayın Tarihi:

11/2018

Belge Dili:

İngilizce

Document ID (Org No.):

2000571600

Sıklık:

İki Yıllık

eISSN:

2651-3722