Synthesis and Characterization of N2O2 Type Schiff Base Ligand with Salicylaldehyde Derivate and Its Metal Complexes

Sümeyra Tuna Yıldırım

Makale detayları

Synthesis and Characterization of N2O2 Type Schiff Base Ligand with Salicylaldehyde Derivate and Its Metal Complexes

Yazarlar:

Sümeyra Tuna Yıldırım

Yayıncı:

Turkish Chemical Society

Ana Başlıklar:

Instrumental Methods | Bioinorganic Chemistry

Dergi:

Journal of the Turkish Chemical Society Section A: Chemistry Vol.11 Issue 3, pp.1091-1098

Belge Tipi:

Makale

Yayın Tarihi:

8/2024

Belge Dili:

İngilizce

Document ID (Org No.):

2001317691

pISSN:

2149-0120

Anahtar kelimeler:

Özet:

 Schiff bases and their metal complexes, which play a role in various biological processes, are one of the most important classes of organic and inorganic compounds. Due to their high use in the field of health, it is important to introduce these compounds into the literature through synthesis and research studies. In this study a new Schiff base ligand was synthesized by the reaction of 4-diethylamino-2-hyrdoxybenzaldehyde with o-aminophenol. This ligand was used to prepare CoII, NiII, CuII and ZnII complexes. The structural characterization of the synthesized ligand and metal complexes was elucidated by various spectroscopic and thermal analysis methods such as FT-IR, 1H-NMR, 13C-NMR, UV-Vis., XRD, SEM and TGA. As a result of these characterization studies, it was determined that the synthesized Schiff base acted as an N2O2 type tetradentate ligand and that the metal ions were bound to the ligand via phenolic oxygen and azomethine nitrogen.

 Schiff bases and their metal complexes, which play a role in various biological processes, are one of the most important classes of organic and inorganic compounds. Due to their high use in the field of health, it is important to introduce these compounds into the literature through synthesis and research studies. In this study a new Schiff base ligand was synthesized by the reaction of 4-diethylamino-2-hyrdoxybenzaldehyde with o-aminophenol. This ligand was used to prepare CoII, NiII, CuII and ZnII complexes. The structural characterization of the synthesized ligand and metal complexes was elucidated by various spectroscopic and thermal analysis methods such as FT-IR, 1H-NMR, 13C-NMR, UV-Vis., XRD, SEM and TGA. As a result of these characterization studies, it was determined that the synthesized Schiff base acted as an N2O2 type tetradentate ligand and that the metal ions were bound to the ligand via phenolic oxygen and azomethine nitrogen.

 Schiff bases and their metal complexes, which play a role in various biological processes, are one of the most important classes of organic and inorganic compounds. Due to their high use in the field of health, it is important to introduce these compounds into the literature through synthesis and research studies. In this study a new Schiff base ligand was synthesized by the reaction of 4-diethylamino-2-hyrdoxybenzaldehyde with o-aminophenol. This ligand was used to prepare CoII, NiII, CuII and ZnII complexes. The structural characterization of the synthesized ligand and metal complexes was elucidated by various spectroscopic and thermal analysis methods such as FT-IR, 1H-NMR, 13C-NMR, UV-Vis., XRD, SEM and TGA. As a result of these characterization studies, it was determined that the synthesized Schiff base acted as an N2O2 type tetradentate ligand and that the metal ions were bound to the ligand via phenolic oxygen and azomethine nitrogen.

 Schiff bases and their metal complexes, which play a role in various biological processes, are one of the most important classes of organic and inorganic compounds. Due to their high use in the field of health, it is important to introduce these compounds into the literature through synthesis and research studies. In this study a new Schiff base ligand was synthesized by the reaction of 4-diethylamino-2-hyrdoxybenzaldehyde with o-aminophenol. This ligand was used to prepare CoII, NiII, CuII and ZnII complexes. The structural characterization of the synthesized ligand and metal complexes was elucidated by various spectroscopic and thermal analysis methods such as FT-IR, 1H-NMR, 13C-NMR, UV-Vis., XRD, SEM and TGA. As a result of these characterization studies, it was determined that the synthesized Schiff base acted as an N2O2 type tetradentate ligand and that the metal ions were bound to the ligand via phenolic oxygen and azomethine nitrogen.

Makale detayları

Synthesis and Characterization of N2O2 Type Schiff Base Ligand with Salicylaldehyde Derivate and Its Metal Complexes

Yazarlar:

Sümeyra Tuna Yıldırım

Yayıncı:

Turkish Chemical Society

Ana Başlıklar:

Instrumental Methods | Bioinorganic Chemistry

Dergi:

Journal of the Turkish Chemical Society Section A: Chemistry Vol.11 Issue 3, pp.1091-1098

Belge Tipi:

Makale

Yayın Tarihi:

8/2024

Belge Dili:

İngilizce

Document ID (Org No.):

2001317691

pISSN:

2149-0120

İmine

Ligand

Metal Complex

Schiff Base

Structural Characterization

Sayı

Makale detayları

Synthesis and Characterization of N2O2 Type Schiff Base Ligand with Salicylaldehyde Derivate and Its Metal Complexes

Yazarlar: Sümeyra Tuna Yıldırım

Yayıncı: Turkish Chemical Society

Ana Başlıklar: Instrumental Methods | Bioinorganic Chemistry

Dergi: Journal of the Turkish Chemical Society Section A: Chemistry Vol.11 Issue 3, pp.1091-1098

Belge Tipi: Makale

Yayın Tarihi: 8/2024

Belge Dili: İngilizce

Document ID (Org No.): 2001317691

pISSN: 2149-0120

İmine

Ligand

Metal Complex

Schiff Base

Structural Characterization

Sayı

Yazarlar:

Sümeyra Tuna Yıldırım

Yayıncı:

Turkish Chemical Society

Ana Başlıklar:

Instrumental Methods | Bioinorganic Chemistry

Dergi:

Journal of the Turkish Chemical Society Section A: Chemistry Vol.11 Issue 3, pp.1091-1098

Belge Tipi:

Makale

Yayın Tarihi:

8/2024

Belge Dili:

İngilizce

Document ID (Org No.):

2001317691

pISSN:

2149-0120