Synthesis, crystal structure, and characterization of two heterometallic   transition metal citrate complexes [M === Co(II) and Cd(II)]

Zeki KARTAL; Onur ŞAHİN; Abdülkerim YAVUZ

Makale detayları

Synthesis, crystal structure, and characterization of two heterometallic transition metal citrate complexes [M === Co(II) and Cd(II)]

Yazarlar:

Zeki KARTAL | Onur ŞAHİN | Abdülkerim YAVUZ

Yayıncı:

TUBITAK

Ana Başlıklar:

Uygulamalı fizik

Dergi:

Turkish Journal of Chemistry 2019 Vol.43 Issue 2, pp.555-567

Belge Tipi:

Makale

Yayın Tarihi:

3/2019

Belge Dili:

İngilizce

Document ID (Org No.):

2000725800

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527

Özet:

 

In this study, two heterometallic transition metal   complexes with the formulas [CoK4(μ104(μ10_{4}(\mu   _{10}-C66_{6}H55_{5}O7)27)2_{7})_{2}]nn_{n} and [CdK(μ8μ8\mu   _{8}-C66_{6}H55_{5}O7)(μ7)(μ_{7})(\mu -H22_{2}O)(H22_{2}O)]nn_{n} were   synthesized as crystalline compounds. The structures of\textbf{   }these crystalline metal complexes were characterized by their   spectral analyses (FT-IR, FT-Raman, thermal analysis, magnetic properties,   and single-crystal X-ray diffraction techniques). According to the spectral   data of the new metal complexes obtained, both metal complexes are in the   monoclinic crystal system and in the P211_{1}/c and P211_{1} space groups,   respectively. The asymmetric unit of the metal complex [CoK4(μ104(μ10_{4}(\mu   _{10}-C66_{6}H55_{5}O7)27)2_{7})_{2}]nn_{n} contains one Co(II)   ion, two potassium cations, and one (C66_{6}H55_{5}O7)7)_{7}) citrate ligand,   whereas that of the asymmetric unit of the metal complex [CdK(μ8μ8\mu   _{8}-C66_{6}H55_{5}O7)(μ7)(μ_{7})(\mu -H22_{2}O)(H22_{2}O)]nn_{n} contains   one Cd(II) ion, one potassium cation, one (C66_{6}H55_{5}O7)7)_{7}) citrate   ligand, and two coordinated water molecules.

Makale detayları

Synthesis, crystal structure, and characterization of two heterometallic transition metal citrate complexes [M === Co(II) and Cd(II)]

Yazarlar: Zeki KARTAL | Onur ŞAHİN | Abdülkerim YAVUZ

Yayıncı: TUBITAK

Ana Başlıklar: Uygulamalı fizik

Dergi: Turkish Journal of Chemistry 2019 Vol.43 Issue 2, pp.555-567

Belge Tipi: Makale

Yayın Tarihi: 3/2019

Belge Dili: İngilizce

Document ID (Org No.): 2000725800

Sıklık: İki Aylık

eISSN: 1303-6130

pISSN: 1300-0527

Sayı

Yazarlar:

Zeki KARTAL | Onur ŞAHİN | Abdülkerim YAVUZ

Yayıncı:

TUBITAK

Ana Başlıklar:

Uygulamalı fizik

Dergi:

Turkish Journal of Chemistry 2019 Vol.43 Issue 2, pp.555-567

Belge Tipi:

Makale

Yayın Tarihi:

3/2019

Belge Dili:

İngilizce

Document ID (Org No.):

2000725800

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527