Organophile element investigations in Miocene bituminous claystones of Ilgın field (Konya): Effect of nutrient input and paleo-productivity

Ali Sarı; Kamal Ismayılzada; Sinan Akıska; Fuat Erol

Makale detayları

Organophile element investigations in Miocene bituminous claystones of Ilgın field (Konya): Effect of nutrient input and paleo-productivity

Yazarlar:

Ali Sarı | Kamal Ismayılzada | Sinan Akıska | Fuat Erol

Yayıncı:

Nigde Omer Halisdemir University

Ana Başlıklar:

Maden Yatakları ve Jeokimya

Dergi:

Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi Vol.13 Issue 4, pp.1168-1183

Belge Tipi:

Makale

Yayın Tarihi:

10/2024

Belge Dili:

Türkçe

Document ID (Org No.):

2001329686

pISSN:

2564-6605

Anahtar kelimeler:

Özet:

 In this study, in addition to P, which is a bionutrient element for phytoplankton algae, during the deposition of bituminous claystones in the Ilgın area, the behavior of elements such as Cu, Ni, Zn, Cd, Ba and Se dissolved in water with organic matter was examined. In addition to nutrients such as N and P, elements such as Cu, Ni, Zn, Cd, Ba and Se act as nutritional elements in the biological productivity of phyto and zooplankton algae in lake and marine environments. The abundance of organic matter TOC in bituminous claystones is closely related to bionutrient elements such as Cu, Ni, Zn, Cd, Ba and Se, which are bound to the organic structure as organometallic ligands, as well as P, which is an algal productive and bionutrient element in the water. In the analyzed samples, TOC exhibits a very weak or weak correlation relationship with Cu r0.122, Ni r0.002, Zn r0.081, Cd r -0.279 and Ba r -0.661 respectively, while displaying a moderately strong correlation with Se r 0.685. This indicates that Selenium specifically exhibits an organophilic element. Moreover, in the examined examples; Cu shows very weak correlations with Fe r 0.220 and S r0.216, Ni shows weak correlations with Fe r 0.029 and S r-0.065, Zn demonstrates weak correlations with Fe r -0.142 and S r -0.135; Cd displays moderate correlations with Fe r 0.379 and S r 0.262; and Ba exhibits very weak correlations with S r -0.515. Conversely, Se shows a strong correlation with Fe r  0.696 and S r  0.732, indicating that only Se is precipitated in the form of sulfide and sulfate compounds. Furthermore, in the analyzed examples; Cu displays a very weak correlation with Mn r  -0.524 and Zn r  -0.163, while Ba shows a strong correlation with Mn r  0.750. This suggests that Ba might have precipitated in the form of Barium Permanganate BaMn2O8.

 In this study, in addition to P, which is a bionutrient element for phytoplankton algae, during the deposition of bituminous claystones in the Ilgın area, the behavior of elements such as Cu, Ni, Zn, Cd, Ba and Se dissolved in water with organic matter was examined. In addition to nutrients such as N and P, elements such as Cu, Ni, Zn, Cd, Ba and Se act as nutritional elements in the biological productivity of phyto and zooplankton algae in lake and marine environments. The abundance of organic matter TOC in bituminous claystones is closely related to bionutrient elements such as Cu, Ni, Zn, Cd, Ba and Se, which are bound to the organic structure as organometallic ligands, as well as P, which is an algal productive and bionutrient element in the water. In the analyzed samples, TOC exhibits a very weak or weak correlation relationship with Cu r0.122, Ni r0.002, Zn r0.081, Cd r -0.279 and Ba r -0.661 respectively, while displaying a moderately strong correlation with Se r 0.685. This indicates that Selenium specifically exhibits an organophilic element. Moreover, in the examined examples; Cu shows very weak correlations with Fe r 0.220 and S r0.216, Ni shows weak correlations with Fe r 0.029 and S r-0.065, Zn demonstrates weak correlations with Fe r -0.142 and S r -0.135; Cd displays moderate correlations with Fe r 0.379 and S r 0.262; and Ba exhibits very weak correlations with S r -0.515. Conversely, Se shows a strong correlation with Fe r  0.696 and S r  0.732, indicating that only Se is precipitated in the form of sulfide and sulfate compounds. Furthermore, in the analyzed examples; Cu displays a very weak correlation with Mn r  -0.524 and Zn r  -0.163, while Ba shows a strong correlation with Mn r  0.750. This suggests that Ba might have precipitated in the form of Barium Permanganate BaMn2O8.

 In this study, in addition to P, which is a bionutrient element for phytoplankton algae, during the deposition of bituminous claystones in the Ilgın area, the behavior of elements such as Cu, Ni, Zn, Cd, Ba and Se dissolved in water with organic matter was examined. In addition to nutrients such as N and P, elements such as Cu, Ni, Zn, Cd, Ba and Se act as nutritional elements in the biological productivity of phyto and zooplankton algae in lake and marine environments. The abundance of organic matter TOC in bituminous claystones is closely related to bionutrient elements such as Cu, Ni, Zn, Cd, Ba and Se, which are bound to the organic structure as organometallic ligands, as well as P, which is an algal productive and bionutrient element in the water. In the analyzed samples, TOC exhibits a very weak or weak correlation relationship with Cu r0.122, Ni r0.002, Zn r0.081, Cd r -0.279 and Ba r -0.661 respectively, while displaying a moderately strong correlation with Se r 0.685. This indicates that Selenium specifically exhibits an organophilic element. Moreover, in the examined examples; Cu shows very weak correlations with Fe r 0.220 and S r0.216, Ni shows weak correlations with Fe r 0.029 and S r-0.065, Zn demonstrates weak correlations with Fe r -0.142 and S r -0.135; Cd displays moderate correlations with Fe r 0.379 and S r 0.262; and Ba exhibits very weak correlations with S r -0.515. Conversely, Se shows a strong correlation with Fe r  0.696 and S r  0.732, indicating that only Se is precipitated in the form of sulfide and sulfate compounds. Furthermore, in the analyzed examples; Cu displays a very weak correlation with Mn r  -0.524 and Zn r  -0.163, while Ba shows a strong correlation with Mn r  0.750. This suggests that Ba might have precipitated in the form of Barium Permanganate BaMn2O8.

 Bu çalışmada Ilgın sahası bitümlü kiltaşlarının çökelimi sırasında fitoplankton algler için biyobesin element olan Pun yanında suda çözünmüş haldeki Cu, Ni, Zn, Cd, Ba ve Se gibi elementlerinin de organik madde ile olan davranışları incelenmiştir. Göl ve denizel ortamlarda fito ve zooplankton alglerin biyolojik üretkenliklerinde N ve P gibi besin elementlerin yanında Cu, Ni, Zn, Cd, Ba ve Se gibi elementlerde besin maddesi elementler olarak davranırlar. Bitümlü kiltaşlarındaki organik madde TOC bolluğu, sudaki algal üretkenik ve biyobesin element olan Pun yanında organik yapıya organometalik ligantlar şeklinde bağlanan Cu, Ni, Zn, Cd, Ba ve Se gibi biyobesin elementlerle de yakın ilişkilidir. Bu amaçla incelenen örneklerde; TOCnin sırasıyla Cu r0.122, Ni r0.002, Zn r0.081, Cd r -0.279 ve Bala r -0.661 çok zayıf veya zayıf, Se r 0.685 ile orta kuvvette korelasyon ilişkisi vardır. Bu durum, sadece Selenyumun organofil bir element olduğunu gösterir. Yine, incelenen örneklerde; Cuın Fe r 0.220 ve S r0.216, Ninin Fe r 0.029 ve S r-0.065, Znnin Fe r -0.142 ve S r -0.135, Cdnin Fe r 0.379 ve S r 0.262 ve Baun S ile r -0.515 çok zayıf; Senin Fe r 0.696 ve S ile r 0.732 kuvvetli korelasyon ilişkisinin olması, sadece Senin sülfidli ve sülfatlı bileşikler şeklinde çökelmiş olduğunu göstermektedir. Yine, incelenen örneklerde; Cunin Mn r -0.52424 ve Zn r-0.16381 ile çok zayıf, Baun Mnla r0.750667 olan kuvvetli korelasyon ilişkisi, ortamda sadece Baun, Baryum Permanganat BaMn2O8 şeklinde çökelmiş olduğunu gösterir.

Makale detayları

Organophile element investigations in Miocene bituminous claystones of Ilgın field (Konya): Effect of nutrient input and paleo-productivity

Yazarlar:

Ali Sarı | Kamal Ismayılzada | Sinan Akıska | Fuat Erol

Yayıncı:

Nigde Omer Halisdemir University

Ana Başlıklar:

Maden Yatakları ve Jeokimya

Dergi:

Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi Vol.13 Issue 4, pp.1168-1183

Belge Tipi:

Makale

Yayın Tarihi:

10/2024

Belge Dili:

Türkçe

Document ID (Org No.):

2001329686

pISSN:

2564-6605

Bituminous Claystone

Organophile Element

Nutrient Input

Paleo-Productivity

Organic MatterBitümlü Kiltaşı

Organofil Element

Besin Girdisi

Paleo-Üretkenlik

Organik Madde

Sayı

Makale detayları

Yazarlar: Ali Sarı | Kamal Ismayılzada | Sinan Akıska | Fuat Erol

Yayıncı: Nigde Omer Halisdemir University

Ana Başlıklar: Maden Yatakları ve Jeokimya

Dergi: Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi Vol.13 Issue 4, pp.1168-1183

Belge Tipi: Makale

Yayın Tarihi: 10/2024

Belge Dili: Türkçe

Document ID (Org No.): 2001329686

pISSN: 2564-6605

Sayı

Yazarlar:

Ali Sarı | Kamal Ismayılzada | Sinan Akıska | Fuat Erol

Yayıncı:

Nigde Omer Halisdemir University

Ana Başlıklar:

Maden Yatakları ve Jeokimya

Dergi:

Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi Vol.13 Issue 4, pp.1168-1183

Belge Tipi:

Makale

Yayın Tarihi:

10/2024

Belge Dili:

Türkçe

Document ID (Org No.):

2001329686

pISSN:

2564-6605